Crystal and molecular structure of diphenyliodonium triiodide

被引：1

作者：

Chernov'yants, M. S. ^{[1
]}

Burykin, I. V. ^{[1
]}

Starikova, Z. A. ^{[2
]}

Rostovskaya, A. A. ^{[1
]}

机构：

[1] So Fed Univ, Rostov Na Donu 344006, Russia

[2] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 57卷 / 02期

关键词：

POLYVALENT IODINE; CHEMISTRY;

D O I：

10.1134/S0036023612020064

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new salt diphenyliodonium triiodide (C12H10I4) was obtained. The [C12H10I+][I (3) (-) ] compound was isolated as red brown crystals and studied by single-crystal X-ray diffraction. The structure of diphenyliodonium triiodide consists of separate, virtually linear I (3) (-) anions and C12H10I+ cations. Strong intermolecular anion-anion (I (3) (-) aEuro broken vertical bar I (3) (-) ) and anion-cation (I (3) (-) aEuro broken vertical bar I+) interactions in the crystal structure leads to a change in the symmetry of triiodide ions. The complex formation in the system organic cation iodide-elementary iodine was studied by spectrophotometry. The complex composition was found (1: 1), and the stability constant of the complex in chloroform was determined (loggB = 3.91).

引用

页码：193 / 196

页数：4

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