Stereoselective Ring-Opening Reactions of Epoxides in Water

被引：21
|
作者：
Bonollo, S. [1 ]
Lanari, D. [1 ]
Marrocchi, A. [1 ]
Vaccaro, L. [1 ]
机构：
[1] Univ Perugia, Lab Green Synthet Organ Chem, CEMIN, Dipartimento Chim, I-06123 Perugia, Italy
来源：
CURRENT ORGANIC SYNTHESIS | 2011年 / 8卷 / 03期
关键词：
Epoxide; water; stereoselective transformations; catalysis; HYDROLYTIC KINETIC RESOLUTION; ASYMMETRIC ALDOL REACTIONS; ORGANIC-REACTIONS; MESO-EPOXIDES; ALPHA; BETA-EPOXYCARBOXYLIC ACIDS; SODIUM-BOROHYDRIDE; SYNTHETIC APPLICATIONS; DIRECTED EVOLUTION; EFFICIENT CATALYST; AROMATIC-AMINES;
D O I：
10.2174/157017911795529191
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Water has proved to be an excellent reaction medium for the definition of highly chemically-efficient and environmentally-friendly synthetic processes. In several cases, by exploiting the unique properties of water it has been possible to realize more selective and efficient processes than those performed in organic media, including the ring-opening of epoxides by nucleophiles. In this review article the role of water in influencing the stereoselectivity of epoxide ring-opening reactions will be presented, including the most recent examples of enzyme-catalyzed processes.
引用
收藏
页码：319 / 329
页数：11
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