Recent Advances on the Photo-Induced Reactions of Acyl Radical

被引:25
|
作者
Ruan, Liheng [1 ]
Chen, Chunxin [1 ]
Zhang, Xiaoxin [1 ]
Sun, Jing [1 ]
机构
[1] Liaoning Shihua Univ, Coll Chem Chem Engn & Environm Engn, Fushun 113001, Peoples R China
关键词
photo-induced; acyl radical; decarboxylation; VISIBLE-LIGHT PHOTOREDOX; ALPHA-OXOCARBOXYLIC ACIDS; C-H ACTIVATION; DECARBOXYLATIVE ORTHO-ACYLATION; METAL-FREE; CARBOXYLIC-ACIDS; CATALYZED HYDROACYLATION; BRANCHED ALDEHYDES; MERGING PHOTOREDOX; COUPLING REACTION;
D O I
10.6023/cjoc201806009
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Recently, the photo-induced radical reactions have emerged as a hot research topic in the field of organic synthetic chemistry. Among these, the radical acylation reaction via photocatalyst is one of the most effecient strategy to prepare ketones under mild conditions. The recent progress on the photo-induced reactions of acyl radical, various acyl radical sources and its application in the organic synthesis is summaried.
引用
收藏
页码:3155 / 3164
页数:10
相关论文
共 85 条
  • [71] Visible-Light-Promoted Synthesis of 1,4-Dicarbonyl Compounds via Conjugate Addition of Aroyl Chlorides
    Wang, Chao-Ming
    Song, Dan
    Xia, Peng-Ju
    Wang, Jing
    Xiang, Hao-Yue
    Yang, Hua
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2018, 13 (03) : 271 - 274
  • [72] Photo-induced Catalytic Asymmetric Free Radical Reactions
    Wang Dehong
    Zhang Long
    Luo Sanzhong
    [J]. ACTA CHIMICA SINICA, 2017, 75 (01) : 22 - 33
  • [73] Decarboxylative 1,4-Addition of α-Oxocarboxylic Acids with Michael Acceptors Enabled by Photoredox Catalysis
    Wang, Guang-Zu
    Shang, Rui
    Cheng, Wan-Min
    Fu, Yao
    [J]. ORGANIC LETTERS, 2015, 17 (19) : 4830 - 4833
  • [74] Metal-Catalyzed Decarboxylative C-H Functionalization
    Wei, Ye
    Hu, Peng
    Zhang, Min
    Su, Weiping
    [J]. CHEMICAL REVIEWS, 2017, 117 (13) : 8864 - 8907
  • [75] Visible Light Photoredox Catalysis Mediated Elementary Steps in Organometallic Reactions
    Wu, Jiang
    Li, Jiawen
    Li, Hao
    Zhu, Chunyin
    [J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (09) : 2203 - 2210
  • [76] Merging Visible-Light Photocatalysis and Palladium Catalysis for C-H Acylation of Azo- and Azoxybenzenes with α-Keto Acids
    Xu, Ning
    Li, Pinhua
    Xie, Zuguang
    Wang, Lei
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (07) : 2236 - 2242
  • [77] Aroyl chlorides as novel acyl radical precursors via visible-light photoredox catalysis
    Xu, Shi-Ming
    Chen, Jian-Qiang
    Liu, Dan
    Bao, Yun
    Liang, Yong-Min
    Xu, Peng-Fei
    [J]. ORGANIC CHEMISTRY FRONTIERS, 2017, 4 (07): : 1331 - 1335
  • [78] Visible-Light-Promoted Asymmetric Cross-Dehydrogenative Coupling of Tertiary Amines to Ketones by Synergistic Multiple Catalysis
    Yang, Qi
    Zhang, Long
    Ye, Chen
    Luo, Sanzhong
    Wu, Li-Zhu
    Tung, Chen-Ho
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (13) : 3694 - 3698
  • [79] Metal-Free Oxidative Decarboxylative Acylation/Ring Expansion of Vinylcyclobutanols with α-Keto Acids by Visible Light Photoredox Catalysis
    Zhang, Jin-Jiang
    Cheng, Yuan-Bo
    Duan, Xin-Hua
    [J]. CHINESE JOURNAL OF CHEMISTRY, 2017, 35 (03) : 311 - 315
  • [80] The synergistic effect of self-assembly and visible-light induced the oxidative C-H acylation of N-heterocyclic aromatic compounds with aldehydes
    Zhang, Lingling
    Zhang, Guoting
    Li, Yongli
    Wang, Shengchun
    Lei, Aiwen
    [J]. CHEMICAL COMMUNICATIONS, 2018, 54 (45) : 5744 - 5747