Indium hydride: a novel radical initiator in the reduction of organic halides with tributyltin hydride

被引：54
|
作者：
Inoue, K [1 ]
Sawada, A [1 ]
Shibata, I [1 ]
Baba, A [1 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Dept Mol Chem, Suita, Osaka 5650871, Japan
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 28期
基金：
日本学术振兴会;
关键词：
indium and compounds; transmetallation; catalysis; radicals and radical reactions;
D O I：
10.1016/S0040-4039(01)00816-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Dichloroindium hydride (Cl2InH), which was generated in situ by transmetallation between tributyltin hydride and indium trichloride, acted as a novel radical initiator for the reduction of organic halides with tributyltin hydride. The reaction was revealed to proceed through a radical process under non-oxygen conditions at room temperature, and to be applicable to intramolecular radical cyclizations. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：4661 / 4663
页数：3
相关论文
共 50 条
12345