Synthesis and photochromic properties of substituted 3H-naphtho[2,1-b]pyrans

被引:38
|
作者
Gabbutt, CD
Heron, BM [1 ]
Instone, AC
Horton, PN
Hursthouse, MB
机构
[1] Univ Leeds, Dept Colour & Polymer Chem, Leeds LS2 9JT, W Yorkshire, England
[2] Univ Southampton, Dept Chem, Southampton S017 1BJ, Hants, England
关键词
naphthopyrans; photochromism; steric effects; X-ray crystallography; synthesis;
D O I
10.1016/j.tet.2004.10.069
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis and spectroscopic properties of novel 3H-naphtho[2, 1-b]pyrans are described. Subtle variation of the colour of the photo-generated merocyanine dyes derived from these naphthopyrans can be accomplished by controlling the steric interactions between a terminal pyrrolidine donor group and a proximal substituent. (C) 2004 Elsevier Ltd. All rights reserved.
引用
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页码:463 / 471
页数:9
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