Advances in 2H-azaphosphirene complex chemistry

被引：0

作者：

Streubel, R ^{[1
]}

Ostrowski, A ^{[1
]}

Wilkens, H ^{[1
]}

Priemer, S ^{[1
]}

Rohde, U ^{[1
]}

机构：

[1] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1997年 / 124卷

关键词：

phosphorus heterocycles; 2H-azaphosphirene complexes; carbene complexes; nitrilium phosphane ylide complexes; phosphanediyl complex;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis of a wide variety of 2H-azaphosphirene pentacarbonyl metal complexes is reported. The overall reaction of this heterocyclic synthesis was determined to be stereospecific, but no asymmetric induction has been observed. Generation, decomposition and trapping reactions of nitrilium phosphane ylide complexes, a zwitterionic acyclic isomer of 2H-azaphosphirene complexes possessing a novel 1,3-dipole system, are presented.

引用

页码：93 / 102

页数：10

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