Bis{μ-dimethyl-1-[1-methoxycarbonyl-3-(methoxyoxalyl)-2-methylpropenyl]-3,3-dimethylcyclopropane-1,2-dicarboxylato(2-)}bis[(triphenylphosphine)palladium(II)] acetone solvate

被引:0
|
作者
Bolte, M
Nass, AR
Hashmi, ASK
机构
[1] Univ Stuttgart, Inst Organ Chem, D-70569 Stuttgart, Germany
[2] Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany
关键词
D O I
10.1107/S1600536805037839
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Pd-2(C18H22O9)(2)(C18H15P)(2)](C3H6O)-C-., features a centrosymmetric dimer and an acetone molecule disordered about a centre of inversion. The Pd coordination is almost square-planar. The central eight-membered ring containing Pd and O atoms adopts a chair conformation, and the six-membered ring containing Pd adopts a half-chair conformation.
引用
收藏
页码:M2677 / M2679
页数:3
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