Effect of temperature on the solubility of 3-aminopyridine in binary ethanol plus toluene solvent mixtures

被引：56
|
作者：
Wei, Dongwei [1 ]
Li, Hui [1 ]
Li, Ya-Nan [1 ]
Zhu, Jing [1 ]
机构：
[1] Tianjin Univ, Res & Dev Ctr Petrochem Technol, Tianjin 300072, Peoples R China
来源：
FLUID PHASE EQUILIBRIA | 2012年 / 316卷
关键词：
Solubility; Solid-liquid equilibrium; Phase equilibrium; 3-Aminopyridine; N-BUTYL ACETATE; 2-AMINOPYRIDINE; ACETONE;
D O I：
10.1016/j.fluid.2011.11.023
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The solubility of 3-aminopyridine in (ethanol + toluene) mixed solvents has been measured between 283.15 and 323.15 K at intervals of 5.00K by a static analytical method. Nonlinear dependences were found for the variation of solubility with temperature. The nonlinear van't Hoff equation was proposed for correlating the experimental data. The apparent molar enthalpies of 3-aminopyridine in the solvent mixtures were determined from the temperature dependence of the solubilities. The values for the apparent Gibbs energy and the apparent entropy of solution are calculated. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：132 / 134
页数：3
相关论文
共 50 条
  • [21] Solubility of anthracene in binary alcohol plus ethyl acetate solvent mixtures
    Toro, A
    Acree, WE
    PHYSICS AND CHEMISTRY OF LIQUIDS, 2002, 40 (03) : 327 - 335
  • [22] Solubility and solution thermodynamics of 2,5-thiophenedicarboxylic acid in (water plus ethanol) binary solvent mixtures
    Yang, Yang
    Zhang, Qi
    Cao, Cuicui
    Cheng, Limin
    Shi, Ying
    Yang, Wenge
    Hu, Yonghong
    THERMOCHIMICA ACTA, 2014, 592 : 52 - 57
  • [23] Solubility Determination and Modeling for Artesunate in Binary Solvent Mixtures of Methanol, Ethanol, Isopropanol, and Propylene Glycol plus Water
    Xu, Renjie
    Han, Ting
    Shen, Li
    Zhao, Jianguo
    Lu, Xiang'an
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2019, 64 (02): : 755 - 762
  • [24] The Importance of Dielectric Constant for Drug Solubility Prediction in Binary Solvent Mixtures: Electrolytes and Zwitterions in Water plus Ethanol
    Fakhree, Mohammad Amin Abolghassemi
    Delgado, Daniel R.
    Martinez, Fleming
    Jouyban, Abolghasem
    AAPS PHARMSCITECH, 2010, 11 (04): : 1726 - 1729
  • [25] Solubility of 3-Aminopyridine in Acetone plus n-Butyl Acetate from (288.15 to 323.15) K
    Wei, Dongwei
    Chen, Limei
    Liu, Cheng
    Zhang, Chao
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (03): : 1163 - 1164
  • [26] Measurement and correlation of solubility of xylitol in binary ethanol plus acetone solvent mixtures with the combined nearly ideal binary Solvent/Redlich-Kister equation
    Wang, Shui
    Li, Qun-Sheng
    Su, Ming-Gao
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (05): : 1733 - 1735
  • [27] Solubility of anthracene in binary alcohol plus 3-methoxy-1-butanol solvent mixtures
    McHale, MER
    Horton, ASM
    Padilla, SA
    Trufant, AL
    DelaSancha, NU
    Vela, E
    Powell, JR
    Acree, WE
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1997, 42 (01): : 54 - 56
  • [28] SOLUBILITY OF ANTHRACENE IN BINARY ALKANE PLUS 3-METHYL-1-BUTANOL SOLVENT MIXTURES
    ZVAIGZNE, AI
    ACREE, WE
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (04): : 708 - 710
  • [29] Thermodynamic analysis and calculation of solubility of Memantine hydrochloride in ethanol plus (acetonitrile, water, ethyl acetate) binary solvent mixtures
    Shen, Fangfang
    Lu, Dingqiang
    Ling, Xiuquan
    Wang, Xinxian
    Liu, Tongqi
    Huang, Tianhua
    He, Kefei
    JOURNAL OF MOLECULAR LIQUIDS, 2017, 229 : 58 - 66
  • [30] SOLUBILITY OF BIPHENYL IN BINARY SOLVENT MIXTURES
    ACREE, WE
    INTERNATIONAL JOURNAL OF PHARMACEUTICS, 1984, 18 (1-2) : 47 - 52
12345