Time dependent interconversion of Diels-Alder adducts into Michael adducts

被引：18
|
作者：
Itoh, K [1 ]
Kitoh, K [1 ]
Sera, A [1 ]
机构：
[1] Kobe Univ, Fac Sci, Dept Chem, Nada Ku, Kobe, Hyogo 6578501, Japan
来源：
HETEROCYCLES | 1999年 / 51卷 / 02期
关键词：
D O I：
10.3987/COM-98-8398
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Furans react with methyl 3-nitroacrylate to concurrently give Diels-Alder adducts and Michael adducts, and the former turns into the latter. The orbital energy difference between a HOMOdiene and a LUMOdienophile seems to control the product distribution of the reaction.
引用
收藏
页码：243 / 248
页数：6
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