(CN3H6)2•(VO2)3(PO4)(HPO4), a layered guanidinium vanadium(V) phosphate related to hexagonal tungsten oxide

被引：53

作者：

Bircsak, Z ^{[1
]}

Harrison, WTA ^{[1
]}

机构：

[1] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 13期

关键词：

D O I：

10.1021/ic9710216

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal synthesis, single-crystal structure, and some physical properties of (CN3H6)(2).(VO2)(3)(PO4)(HPO4), a new guanidinium vanadium(V) phosphate, are reported. This phase is built up from vertex-sharing layers of VO6 octahedra, which adopt the hexagonal tungsten oxide motif. These octahedral layers are capped by P-O and P-OH entities resulting in anionic layers of stoichiometry [(VO)(3)(PO4)(HPO4)](2-). Pairs of guanidinium cations are arrayed in the interlayer regions in a manner that suggests interactions may occur between these species. Crystal data consists of the following:. (CN3H6)(2).(VO2)(3)(PO4)(HPO4), monoclinic, C2/c (No. 15), a = 12.446(3) Angstrom, b = 7.287(2) Angstrom, c = 17.819(5) Angstrom, beta = 97.23(3)degrees, Z = 4.

引用

页码：3204 / 3208

页数：5

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