Electrochemical Properties of a Gold Nanoseed Particle-Attached Nickel Electrode

被引:0
|
作者
Uemoto, Takahiro [1 ]
Nakayama, Yosuke [1 ]
Chen, Xiaomei [1 ,2 ]
Chang, Gang [3 ]
Oyama, Munetaka [1 ]
机构
[1] Kyoto Univ, Dept Chem Mat, Grad Sch Engn, Nishikyo Ku, Kyoto 6158520, Japan
[2] Jimei Univ, Coll Food & Biol Engn, Xiamen 361021, Peoples R China
[3] Hubei Univ, Minist Educ, Key Lab Green Preparat & Applicat Funct Mat, Fac Mat Sci & Engn, Wuhan 430062, Peoples R China
基金
日本学术振兴会;
关键词
Gold; Nanoparticles; Nickel; Modified electrode; Electrocatalysis; SEED MEDIATED GROWTH; NANOPARTICLES; ELECTROANALYSIS; METAL; OXIDATION; NANORODS; GLUCOSE;
D O I
10.1002/elan.201400570
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Gold nanoseed particles (AuNSPs) of ca. 3.5 nm were attached on a Ni disk electrode, and the electrochemical properties of the thus-prepared AuNSP-attached nickel (AuNSP/Ni) electrode were investigated. As a remarkable effect of AuNSPs, cyclic voltammograms of Fe(CN)(6)(4-) recorded with an AuNSP/Ni electrode was reversible and almost identical to those recorded with an Au disk electrode, while a reversible response was not observed with a Ni disk electrode. The similar tendency was observed for the electrochemical oxidation of uric acid and glucose. Also, AuNSPs was proved to suppress the redox reactions of the Ni electrode in alkaline solutions.
引用
收藏
页码:964 / 969
页数:6
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