X-ray powder diffraction and solid-state NMR investigations in cadmium-lead hydroxyapatites

被引：0

作者：

Badraoui, B

Bigi, A ^{[1
]}

Debbabi, M

Gazzano, M

Roveri, N

Thouvenot, R

机构：

[1] Ecole Natl Ingn Monastir, Lab Chim Inorgan & Ind, Monastir 5019, Tunisia

[2] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[3] CNR, Ctr Studio Fis Macromol, I-40126 Bologna, Italy

[4] Univ Paris 06, Unite CNRS 7071, Lab Chim Inorgan & Mat Mol, F-75252 Paris 05, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2001年 / 05期

关键词：

hydroxyapatite; Rietveld method; P-31 MAS NMR spectroscopy; ionic substitution; X-ray diffraction;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the proposed experiment, the maximum amount of cadmium substitution in lead hydroxyapatite accounts for about to 30 atom-%. The crystal structures of PbHA at different degrees of cadmium substitution for lead (4.9, 10.0, 22.4 and 29.0% Cd atoms) have been investigated by X-ray powder pattern fitting and P-31 MAS NMR. The site-occupancy factors of metal atoms clearly indicate a preference of cadmium for site 1 of the apatite structure, which is more selective at low cadmium content. A progressive shift of the OH group wards the center of the triangles formed by the site 2 metalshas been observed with increasing cadmium content. The different environments of the phosphate group demonstrated by P-31 NMR spectroscopic data are discussed in relation to structural data.

引用

页码：1261 / 1267

页数：7

共 50 条

[41] The stoichiometry of synthetic alunite as a function of hydrothermal aging investigated by solid-state NMR spectroscopy, powder X-ray diffraction and infrared spectroscopy
Elisabeth Grube
Ulla Gro Nielsen
Physics and Chemistry of Minerals, 2015, 42 : 337 - 345
[42] The stoichiometry of synthetic alunite as a function of hydrothermal aging investigated by solid-state NMR spectroscopy, powder X-ray diffraction and infrared spectroscopy
Grube, Elisabeth
Nielsen, Ulla Gro
PHYSICS AND CHEMISTRY OF MINERALS, 2015, 42 (05) : 337 - 345
[43] Solid-state NMR and powder X-ray diffraction studies on ammonium ion-exchanged and dealuminated zeolite YNU-5
Ikeda, Takuji
Yoshida, Yuka
Nakazawa, Naoto
Inagaki, Satoshi
Kubota, Yoshihiro
MICROPOROUS AND MESOPOROUS MATERIALS, 2020, 302
[44] Quantification of compaction-induced crystallinity reduction of a pharmaceutical solid using 19F solid-state NMR and powder X-ray diffraction
Liu, Jodi
Nagapudi, Karthik
Kiang, Y. -H.
Martinez, Ezequiel
Jona, Janan
DRUG DEVELOPMENT AND INDUSTRIAL PHARMACY, 2009, 35 (08) : 969 - 975
[45] Solid-state NMR and X-ray diffraction studies of the geometry and intramolecular dynamics of bis(organothiophosphoryl) dichalcogenides
Potrzebowski, MJ
Blaszczyk, J
Wieczorek, MW
Klinowski, J
JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (43): : 8077 - 8084
[46] Phenyl glycosides - Solid-state NMR, X-ray diffraction and conformational analysis using genetic algorithm
Walejko, Piotr
Bukowicki, Jaroslaw
Dobrzycki, Lukasz
Socha, Pawel
Paradowska, Katarzyna
CHEMICAL PHYSICS, 2019, 519 : 126 - 136
[47] Solid-state NMR and x-ray diffraction studies of the geometry and intramolecular dynamics of bis(organothiophosphoryl) dichalcogenides
Polish Acad of Sciences, Lodz, Poland
J Phys Chem A, 43 (8077-8084):
[48] Revisiting the crystal structure of dickite: X-ray diffraction, solid-state NMR, and DFT calculations study
Rocha, Joao
Almeida Paz, Filipe A.
Sardo, Mariana
Mafra, Luis
AMERICAN MINERALOGIST, 2018, 103 (05) : 812 - 818
[49] Polymorphism in Xaliproden (SR57746A): An X-ray Diffraction, Calorimetric, and Solid-State NMR Investigation
Chandrappa, Ravi Kumar
Ochsenbein, Philippe
Martineau, Charlotte
Bonin, Michel
Althoff, Gerhard
Engelke, Frank
Malandrin, Harold
Castro, Bertrand
El Hajji, Mohamed
Taulelle, Francis
CRYSTAL GROWTH & DESIGN, 2013, 13 (11) : 4678 - 4687
[50] X-ray powder diffraction investigations of phenol derivatives
Rafalska-Lasocha, A
Wlodarczyk-Gajda, B
Grzywa, M
Lasocha, W
POWDER DIFFRACTION, 2004, 19 (03) : 292 - 295

← 1 2 3 4 5 →