Synthesis of 2-phosphoro-1,2-thiazetidine 1,1-dioxide

被引：0
|
作者：
Mielniczak, G [1 ]
Lopusinski, A [1 ]
机构：
[1] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland
来源：
HETEROATOM CHEMISTRY | 1999年 / 10卷 / 01期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reactions of phosphorochloridites 5a-c with an equimolar amount of 1,2-thiazetidine 1,1-dioxide (2) or L(-)-3-carboethoxy-1,2-thiazetidine 1,1-dioxide (7) in the presence of triethylamine, affords the N-phosphitylated beta-sultams 6a-b and L(-)-8a,c. Their oxidation by addition of oxygen, sulfur, or selenium results in formation of stable organophosphorus beta-sultams 10a-b, L(-)-11a,c, 12a, 13a, L(-)-14c, and L( -)-15c. (C) 1999 John Wiley & Sons, Inc.
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页码：61 / 67
页数：7
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