Study of Magnesium-Containing Zeolite Catalysts for the Synthesis of Lower Olefins from Dimethyl Ether

被引:25
|
作者
Goryainova, T. I. [1 ]
Biryukova, E. N. [1 ]
Kolesnichenko, N. V. [1 ]
Khadzhiev, S. N. [1 ]
机构
[1] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119991, Russia
关键词
Zeolite; Space Velocity; Dimethyl Ether; Isobutane; Petroleum Chemistry;
D O I
10.1134/S096554411101004X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The catalytic properties of magnesium-containing zeolite catalysts in the synthesis of olefins from dimethyl ether (DME) were studied. The optimal concentrations of magnesium in the zeolite catalyst were found, and a procedure for its introduction was developed. The effect of the operation conditions of DME conversion into lower olefins on the catalyst activity and selectivity was studied. The stability of the catalytic properties of the synthesized catalyst after oxidative regeneration was examined.
引用
收藏
页码:169 / 173
页数:5
相关论文
共 50 条
  • [41] Study on Catalysts for Direct Synthesis of Dimethyl Ether from Bio-Syngas
    Xu, Haiyan
    Ren, Suxia
    Lei, Tingzhou
    Zhu, Jinling
    JOURNAL OF BIOBASED MATERIALS AND BIOENERGY, 2015, 9 (01) : 62 - 65
  • [42] DIRECT SYNTHESIS OF METHANOL, DIMETHYL ETHER, AND PARAFFINS FROM SYNGAS OVER PD/ZEOLITE Y-CATALYSTS
    CAVALCANTI, FAP
    STAKHEEV, AY
    SACHTLER, WMH
    JOURNAL OF CATALYSIS, 1992, 134 (01) : 226 - 241
  • [43] METHYL-TERT-BUTYL ETHER SYNTHESIS ON ZEOLITE-CONTAINING CATALYSTS
    RUSTAMOV, MI
    GUSEINOVA, AD
    ASKERZADE, SM
    YUNUSOV, SG
    KHIMICHESKAYA PROMYSHLENNOST, 1986, (06): : 327 - 328
  • [44] Zr- and La-containing Catalysts in Synthesis of Methanol and Dimethyl Ether
    M. A. Kipnis
    A. P. Kosolapova
    I. A. Belostotskii
    E. A. Volnina
    G. N. Bondarenko
    I. S. Levin
    A. B. Ponomarev
    Russian Journal of Applied Chemistry, 2019, 92 : 1084 - 1093
  • [45] Zr- and La-containing Catalysts in Synthesis of Methanol and Dimethyl Ether
    Kipnis, M. A.
    Kosolapova, A. P.
    Belostotskii, I. A.
    Volnina, E. A.
    Bondarenko, G. N.
    Levin, I. S.
    Ponomarev, A. B.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2019, 92 (08) : 1084 - 1093
  • [46] Rhodium-Chitosan Composites Supported on Magnesium-HZSM-5 in the Conversion of Dimethyl Ether to Lower Olefins
    Kolesnichenko, N. V.
    Kolesnikova, E. E.
    Obukhova, T. K.
    Bondarenko, G. N.
    PETROLEUM CHEMISTRY, 2018, 58 (12) : 1013 - 1018
  • [47] DEVELOPMENT OF CATALYSTS FOR SYNTHESIZING DIMETHYL ETHER FROM SYNTHESIS GAS
    SHI Ren-Min
    CAI Guang-Yu
    LIU Zhong-Min
    SUN Cheng-Lin(Dalian Institute of Chemical Physics
    Journal of Natural Gas Chemistry, 1996, (04) : 287 - 295
  • [48] Zeolite-based bifunctional catalysts for the single step synthesis of dimethyl ether from CO-rich synthesis gas
    Ahmad, Ruaa
    Schrempp, David
    Behrens, Silke
    Sauer, Joerg
    Doering, Manfred
    Arnold, Ulrich
    FUEL PROCESSING TECHNOLOGY, 2014, 121 : 38 - 46
  • [49] Interfacial study of magnesium-containing fluoridated hydroxyapatite coatings
    Cai, Yanli
    Zhang, Sam
    Zeng, Xianting
    Qian, Min
    Sun, Deen
    Weng, Wenjian
    THIN SOLID FILMS, 2011, 519 (15) : 4629 - 4633
  • [50] Study on kinetics of bioethanol to dimethyl ether conversion on copper-modified zeolite catalysts
    Nazimek, Dobieslaw
    Zajac, Grzegorz
    Slowik, Tomasz
    Kuranc, Andrzej
    Krzaczek, Pawel
    Szyszlak-Barglowicz, Joanna
    Piekarski, Wieslaw
    Marczuk, Andrzej
    PRZEMYSL CHEMICZNY, 2015, 94 (10): : 1778 - 1782