Preparation and properties of biobased autocatalytic polyols and their polyurethane foams

被引：30
|
作者：
Huo, Shuping [1 ,2 ]
Jin, Can [1 ]
Liu, Guifeng [1 ]
Chen, Jian [1 ]
Wu, Guomin [1 ,2 ]
Kong, Zhenwu [1 ,2 ]
机构：
[1] CAF, Inst Chem Ind Forest Prod, Natl Engn Lab Biomass Chem Utilizat,SFA, Key & Open Lab Forest Chem Engn,Key Lab Biomass E, Nanjing 210042, Jiangsu, Peoples R China
[2] CAF, Inst New Technol Forestry, Beijing 100091, Peoples R China
来源：
POLYMER DEGRADATION AND STABILITY | 2019年 / 159卷
关键词：
Polyurethane foam; Cardanol; Autocatalytic; Polyols; TG-FTIR-MS; THERMAL-DEGRADATION; FLAME-RETARDANT; CARDANOL; OIL; PYROLYSIS; PHOSPHATE; POLYMERS; AGENT; STRAW;
D O I：
10.1016/j.polymdegradstab.2018.11.019
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
In the present work, we developed a green and more efficient method to prepare biobased polyurethane (PU) foams under catalyst-free condition. Firstly, novel organositicon grafting cardanol-based autocatalytic polyols (SCAPs) with low viscosity were synthesized through the ring opening of cardanol glycidyl ether (CGE) and the hydrosilation of unsaturated alkyl chain with heptamethyltrisiloxane (HMTS). Subsequently, PU foams were synthesized by SCAPs in absence of catalyst. The structure and properties of the PU foams were evaluated and discussed. In addition, the thermal degradation mechanism of PU foams was investigated by using a thermogravimetric analysis instrument coupled with fourier transform infrared and mass spectrometer (TG-FFIR-MS). The results showed that the PU foams had high compression strength and thermo-stability. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码：62 / 69
页数：8
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