New Example of Metal-Containing Monomers for Frontal Polymerization

被引：12
|
作者：
Uflyand, Igor E. [1 ]
Zhinzhilo, Vladimir A. [1 ]
Dzhardimalieva, Gulzhian, I [2 ]
机构：
[1] Southern Fed Univ, Dept Chem, B Sadovaya Str 105-42, Rostov Na Donu 344006, Russia
[2] RAS, Inst Problems Chem Phys, Lab Metallopolymers, Chernogolovka 142432, Moscow Region, Russia
来源：
CHEMISTRYSELECT | 2019年 / 4卷 / 07期
关键词：
cinnamates; frontal polymerization; metal-containing monomer; nanomaterial; thermolysis; CHELATE MONOMERS; COMPLEXES; THERMOLYSIS; NANOPARTICLES; DERIVATIVES; COMPOSITES; COPPER(II); INHIBITORS; CINNAMATE; CO(II);
D O I：
10.1002/slct.201803894
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the present work, new metal-containing monomers based on copper(II) cinnamate (cinn), viz.: [Cu(cinn)(2)(bpy)(C2H5OH)], [Cu(cinn)(2)(phen)(H2O)(2)], and [Cu(cinn)(2)(tpy)(C2H5OH)(2)] (bpy = 2,2 '-bipyridine, phen=1,10-phenanthroline and tpy=4 '-phenyl-2,2 ':6 ',2 ''-terpyridine) were synthesized. At the first time, it was shown that these metal-containing monomers undergo frontal polymerization.
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页码：2105 / 2108
页数：4
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