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Nanoparticle Oscillations and Fronts
被引:111
|作者:
Lagzi, Istvan
[1
]
Kowalczyk, Bartlomiej
[1
]
Wang, Dawei
[1
,2
]
Grzybowski, Bartosz A.
[1
]
机构:
[1] Northwestern Univ, Dept Chem, Dept Chem & Biol Engn, Evanston, IL 60208 USA
[2] NW Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Peoples R China
关键词:
front propagation;
nanoparticles;
nonlinear chemical dynamics;
oscillations;
self-assembly;
OPPOSITELY CHARGED NANOPARTICLES;
SELF-ASSEMBLED MONOLAYERS;
METAL NANOPARTICLES;
PH OSCILLATIONS;
AGGREGATION;
FORCES;
PRECIPITATION;
PATTERNS;
DESIGN;
SYSTEM;
D O I:
10.1002/anie.201004231
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Rhythmic nanoparticles: Chemical oscillations can be coupled to the dynamic self-assembly of nanoparticles. Periodic pH changes translate into protonation and deprotonation of the ligands that stabilize the nanoparticles, thus altering repulsive and attractive interparticle forces. In a continuous stirred-tank reactor, rhythmic aggregation and dispersion is observed; in spatially distributed media, propagation of particle aggregation fronts is seen. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码:8616 / 8619
页数:4
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