Acetylene Solubility in High-Energy-Density Fuels Enhanced by Amines and Scrambled Cages

被引：2

作者：

Xiu-tian-feng, E. ^{[1
,2
]}

Zhang, Lei ^{[1
,2
]}

Pan, Lun ^{[1
,2
]}

Zou, Ji-Jun ^{[1
,2
]}

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, Minist Educ, Key Lab Green Chem Technol, Tianjin, Peoples R China

[2] Collaborat & Innovat Ctr Chem Sci & Engn, Tianjin, Peoples R China

来源：

CHEMISTRY AND TECHNOLOGY OF FUELS AND OILS | 2018年 / 54卷 / 05期

基金：

中国国家自然科学基金;

关键词：

acetylene solubility; JP-10; quadricyclane; Et3N; scrambled cages; PARTICLE COMBUSTION; LIQUID; IGNITION; TRICYCLOPENTADIENE; REARRANGEMENT; HYDROCARBON; KINETICS;

D O I：

10.1007/s10553-018-0965-0

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

High-energy-density (HED) fuels are widely used in aerospace engines bit suffer front slow trance and incomplete combustion. A proposed solution to this problem is dissolution of a flammable small-molecule additive, a g., acetylene, in the fuel. The solubility of acetylene in HED fuels JP-10 and QC at 298.15 K and pressure from 0 to 200 kPa was studied. The molar concentration of acetylene in JP-10 and QC fuels or a pressure of 100 kPa reached 0.60 and 0.75%, respectively. Studies of the dissolution of acetylene in the presence of Et3N and scrambled cages (1, 2, and 5 mass%) showed that such additives could increase significantly the solubility of acetylene in the fuel. The research results are of practical interest for improving the efficiency of HED fuels.

引用

页码：599 / 605

页数：7

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