Di-μ-chloro-bis[chloro(η5-indenyl)methyl-hafnium(IV)]

被引:1
|
作者
Morris, RJ [1 ]
Shaw, SL
Huffman, JC
Bollinger, JC
机构
[1] Ball State Univ, Dept Chem, Muncie, IN 47306 USA
[2] Indiana Univ, Dept Chem, Ctr Mol Struct, Bloomington, IN 47405 USA
关键词
D O I
10.1107/S0108270198005368
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The molecular structure of the title complex, [HfCl(mu- Cl)(CH3)(eta(5)-C9H7)](2), which is a rare example of an indenylhafnium alkyl complex, is described. In this centrosymmetric structure, the geometry around each Hf atom is best described as a pseudo-square pyramid. There is a small amount of disorder between the methyl groups and the terminal chloride ligands.
引用
收藏
页码:1617 / 1618
页数:2
相关论文
共 50 条
  • [31] Di-μ-chloro-bis{chloro[1,2-diphenyl-2-(4-chlorophenylamino)ethanoximato]copper(II)}
    Puschmann, H
    Howard, JAK
    Soto, B
    Bonne, R
    Au-Alvarez, O
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : M551 - M552
  • [32] trans-Di-μ-chloro-bis[chloro(tricyclohexylphosphine)palladium] benzene solvate
    Sui-Seng, C
    Bélanger-Gariépy, F
    Zargarian, D
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M620 - M621
  • [33] Di-μ-chloro-bis{chloro[hydrotris(pyrazol-1-yl)borato)](tetrahydrofuran) ytterbium(III)} toluene solvate
    Rabe, Gerd W.
    Zhang-Presse, Mei
    Riederer, Florian A.
    Rheingold, Arnold L.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M3149 - M3151
  • [34] Di-μ-chloro-bis{chloro[2-(4-methylphenylamino)-1,2-diphenylethanoximato]copper(II)}
    Puschmann, H
    Howard, JAK
    Soto, B
    Bonne, R
    Au-Alvarez, O
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : M581 - M583
  • [35] Di-μ-chloro-bis[1,2-bis(diphenylphosphino)-ethanepalladium(II)]:: Synthesis and crystal structure
    Kumar, JS
    Singh, AK
    Yang, JC
    Drake, JE
    JOURNAL OF COORDINATION CHEMISTRY, 1998, 44 (3-4) : 335 - 342
  • [36] Di-μ-chloro-bis[(N-tert-butylimido)chlorobis-(pyridine-κN)titaniurn(IV)] perdeuterobenzene disolvate
    Hazari, N
    Cowley, AR
    Mountford, P
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M1844 - M1846
  • [37] Di-μ-chloro-bis[chloro(phenyl 2-pyridyl ketone oxime-κ2N,N′)copper(II)]
    Xiang, Jing
    Li, Qin
    Mei, Ping
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M2348 - M2349
  • [38] Trans-di-μ-chloro-bis[chloro(trimethyl-phosphine-P) platinum(II)]
    Boag, Neil M.
    Ravetz, Megan S.
    Acta Crystallographica, Section C: Crystal Structure Communications, 1996, 52 (pt 8): : 1942 - 1943
  • [39] Octabutylbis(μ2-2-chloro-5-nitrobenzoato)bis(2-chloro-5-nitrobenzoato)di-μ3-oxido-tetratin(IV)
    Win, Yip-Foo
    Choong, Chen-Shang
    Ha, Sie-Tiong
    Goh, Jia Hao
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1698 - U1930
  • [40] Inhibition of a palladium(II) catalyst upon formation of a di-μ-chloro complex:: di-μ-chloro-bis[1,2-bis(diphenylphosphino)ethane-P,P′]-dipalladium(II) bis(tetrafluoroborate) bis(deuterochloroform) solvate
    Abu-Surrah, AS
    Klinga, M
    Repo, T
    Leskelä, M
    Debaerdemaeker, T
    Rieger, B
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 : E44 - E45