Tetrahedral metal-organic cages with cube-like cavities for selective encapsulation of fullerene guests and their spin-crossover properties

被引：37

作者：

Han, Wang-Kang ^{[1
]}

Zhang, Hai-Xia ^{[1
]}

Wang, Yong ^{[2
]}

Liu, Wei ^{[2
]}

Yan, Xiaodong ^{[1
]}

Li, Tao ^{[1
]}

Gu, Zhi-Guo ^{[1
,3
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Synthet & Biol Colloids, Wuxi 214122, Peoples R China

[2] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

[3] Jiangnan Univ, Sch Chem & Mat Engn, Int Joint Res Ctr Photorespons Mol & Mat, Wuxi 214122, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 89期

基金：

中国国家自然科学基金;

关键词：

MOLECULAR CAGES; BINDING; ADSORPTION; FRAMEWORKS; DESIGN;

D O I：

10.1039/c8cc06652c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetrahedral FeII4L(6) coordination cages containing organic linkers with rigid -electron aromatic rings and flexible alkyl units were constructed. Interestingly, these tetrahedral cages have rare cube-like cavities for selective encapsulation of fullerene guests. In addition, the solid state spin-crossover properties were influenced by guest binding of fullerene C-60.

引用

页码：12646 / 12649

页数：4

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