Tetrahedral metal-organic cages with cube-like cavities for selective encapsulation of fullerene guests and their spin-crossover properties

被引：37
|
作者：
Han, Wang-Kang [1 ]
Zhang, Hai-Xia [1 ]
Wang, Yong [2 ]
Liu, Wei [2 ]
Yan, Xiaodong [1 ]
Li, Tao [1 ]
Gu, Zhi-Guo [1 ,3 ]
机构：
[1] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Synthet & Biol Colloids, Wuxi 214122, Peoples R China
[2] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
[3] Jiangnan Univ, Sch Chem & Mat Engn, Int Joint Res Ctr Photorespons Mol & Mat, Wuxi 214122, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 89期
基金：
中国国家自然科学基金;
关键词：
MOLECULAR CAGES; BINDING; ADSORPTION; FRAMEWORKS; DESIGN;
D O I：
10.1039/c8cc06652c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Tetrahedral FeII4L(6) coordination cages containing organic linkers with rigid -electron aromatic rings and flexible alkyl units were constructed. Interestingly, these tetrahedral cages have rare cube-like cavities for selective encapsulation of fullerene guests. In addition, the solid state spin-crossover properties were influenced by guest binding of fullerene C-60.
引用
收藏
页码：12646 / 12649
页数：4
相关论文
共 50 条
  • [1] Illuminating spin-crossover octanuclear metal-organic cages
    Zhi-Kun Liu
    Alyona A. Starikova
    Yu-Xia Li
    Ke Sun
    Meng Yu
    Zi-Shuo Yao
    Jun Tao
    Science China Chemistry, 2024, 67 : 1208 - 1215
  • [2] Illuminating spin-crossover octanuclear metal-organic cages
    Liu, Zhi-Kun
    Starikova, Alyona A.
    Li, Yu-Xia
    Sun, Ke
    Yu, Meng
    Yao, Zi-Shuo
    Tao, Jun
    SCIENCE CHINA-CHEMISTRY, 2024, 67 (04) : 1208 - 1215
  • [3] Illuminating spin-crossover octanuclear metal-organic cages
    Zhi-Kun Liu
    Alyona A.Starikova
    Yu-Xia Li
    Ke Sun
    Meng Yu
    Zi-Shuo Yao
    Jun Tao
    Science China(Chemistry), 2024, (04) : 1208 - 1215
  • [4] Tuning the spin-crossover properties of [Fe2] metal-organic cages
    Navarro, Laia
    Garcia-Duran, Arnau
    Cirera, Jordi
    DALTON TRANSACTIONS, 2024, 53 (35)
  • [5] Spin-crossover complex encapsulation within a magnetic metal-organic framework
    Abherve, Alexandre
    Grancha, Thais
    Ferrando-Soria, Jesus
    Clemente-Leon, Miguel
    Coronado, Eugenio
    Waerenborgh, Joao C.
    Lloret, Francesc
    Pardo, Emilio
    CHEMICAL COMMUNICATIONS, 2016, 52 (46) : 7360 - 7363
  • [6] Tunable cooperativity in a spin-crossover Hoffman-like metal-organic framework material by aromatic guests
    Li, Jin-Yan
    He, Chun-Ting
    Chen, Yan-Cong
    Zhang, Ze-Min
    Liu, Wei
    Ni, Zhao-Ping
    Tong, Ming-Liang
    JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (30) : 7830 - 7835
  • [7] Bivariate Metal-Organic Frameworks with Tunable Spin-Crossover Properties
    Gong, Yu
    Li, Zhi-Hua
    Yan, Xiaodong
    Wang, Ya-Qin
    Zhao, Chen-Yang
    Han, Wang-Kang
    Hu, Qing-Tao
    Lu, Hui-Shu
    Gu, Zhi-Guo
    CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (54) : 12472 - 12480
  • [8] Metal-center exchange of tetrahedral cages: single crystal to single crystal and spin-crossover properties
    Zhang, Feng-Li
    Chen, Jia-Qian
    Qin, Long-Fang
    Tian, Lei
    Li, Zaijun
    Ren, Xuehong
    Gu, Zhi-Guo
    CHEMICAL COMMUNICATIONS, 2016, 52 (26) : 4796 - 4799
  • [9] A Paramagnetic NMR Spectroscopy Toolbox for the Characterisation of Paramagnetic/Spin-Crossover Coordination Complexes and Metal-Organic Cages
    Lehr, Marc
    Paschelke, Tobias
    Trumpf, Eicke
    Vogt, Anna-Marlene
    Naether, Christian
    Soennichsen, Frank D.
    McConnell, Anna J.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (43) : 19344 - 19351
  • [10] Proton-Induced Reversible Spin-State Switching in Octanuclear FeIII Spin-Crossover Metal-Organic Cages
    Liu, Zhi-Kun
    Ji, Xue-Yang
    Yu, Meng
    Li, Yu-Xia
    Hu, Jie-Sheng
    Zhao, Yu-Meng
    Yao, Zi-Shuo
    Tao, Jun
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (31) : 22036 - 22046
12345