Addition of Organometallic Nucleophiles (Carbonylmetallates) to the Allyl Ligand of [(η3-C3H5)Pd(μ-Cl)]2. Synthesis and Structure of (η3-C3H5)Mn(CO)3PEt3

被引：0

作者：

Kerscher, Thomas ^{[1
]}

Mihan, Shahram ^{[1
]}

Beck, Wolfgang ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2011年 / 66卷 / 08期

关键词：

Allyl; Carbonyl; Palladium; Manganese; X-Ray Structure Determination; METAL-METAL BONDS; CRYSTAL-STRUCTURE; CATIONIC ALLYL; LEWIS-ACIDS; COMPLEXES; MANGANESE; ATTACK; MOLYBDENUM; CHEMISTRY; IRON;

D O I：

10.5560/ZNB.2011.66b0861

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the organometallic nucleophile [Mn(CO)(4)-PEt3](-) at the allyl ligand of [(eta(3)-C3H5)Pd(mu-Cl)](2) proceeds by allyl transfer from Pd(II) to Mn(-I) to give [(eta(3)-C3H5)-Mn(CO)(3)PEt3], of which the structure has been determined by X-ray diffraction.

引用

页码：861 / 864

页数：4

共 50 条

[41] Electron-Induced Surface Reactions of η3-Allyl Ruthenium Tricarbonyl Bromide [(η3-C3H5)Ru(CO)3Br]: Contrasting the Behavior of Different Ligands
Spencer, Julie A.
Brannaka, Joseph A.
Barclay, Michael
McElwee-White, Lisa
Fairbrother, D. Howard
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (27): : 15349 - 15359
[42] Mono- and binuclear bipyridyl derivatives of the Mo(η3-C3H5)(CO)2 fragment:: structural studies and fluxionality in solution
Costa, PMFJ
Mora, M
Calhorda, MJ
Félix, V
Ferreira, P
Drew, MGB
Wadepohl, H
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 687 (01) : 57 - 68
[43] Density functional theory investigation into the mechanism for η2-alkyne to vinylidene isomerization by the addition of phenylacetylene to [(η3-C3H5)Rh(PiPr3)2]
Vastine, Benjamin Alan
Hall, Michael B.
ORGANOMETALLICS, 2008, 27 (17) : 4325 - 4333
[44] Efficient NH3-based process to remove chlorine from electron beam deposited ruthenium produced from (η3-C3H5)Ru(CO)3Cl
Markus Rohdenburg
Hannah Boeckers
Christopher R. Brewer
Lisa McElwee-White
Petra Swiderek
Scientific Reports, 10
[45] Efficient NH3-based process to remove chlorine from electron beam deposited ruthenium produced from (η3-C3H5)Ru(CO)3Cl
Rohdenburg, Markus
Boeckers, Hannah
Brewer, Christopher R.
McElwee-White, Lisa
Swiderek, Petra
SCIENTIFIC REPORTS, 2020, 10 (01)
[46] The structure of [Co3(η5-C5H5)3(μ3-S)(μ3-CSMe)]+, and the reactions of the metal cluster cations [{Co(η5-C5H5)}2{Fe(CO)2(PPh3)}-(μ3-S)μ3-CSR)]+ and [{Co(η5-C5H5)}3(μ3-S)(μ3-CSR)]+ (R = Me, Et) with nucleophiles
Cromhout, NL
Manning, AR
Palmer, AJ
McAdam, CJ
Robinson, BH
Simpson, J
INORGANICA CHIMICA ACTA, 2003, 354 : 54 - 60
[47] X-RAY AND CONFORMATION ANALYSIS OF THE NEW TRINUCLEAR CLUSTER OF OSMIUM Os3(μ,η2-OCC6H5)(η3-C3H5)(CO)9
Maksakov, V. A.
Pervukhina, N. V.
Podberezskaya, N. V.
Afonin, M. Yu.
Potemkin, V. A.
Kirin, V. P.
JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 49 (05) : 894 - 900
[48] Modeling η5-C5Me4SiMe3 with η3-C3H5 for DFT study of a tetranuclear yttrium polyhydrido complex [(η5-C5Me4SiMe3)YH2]4
Luo, Yi
Hou, Zhaomin
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2007, 107 (02) : 374 - 381
[49] LIGAND SUBSTITUTION-REACTIONS OF THE ORGANOMETALLIC RADICAL [ETA-3C3H5FE(CO)3]
GOULIN, CA
BAIRD, MC
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 710 - INOR
[50] Simple organometallic alcohols: Synthesis of (C5H4OH)Mn(CO)(3) (hydroxycymantrene) and (C5H4OH)W(CO)(3)CH3
Plenio, H
Warnecke, A
ORGANOMETALLICS, 1996, 15 (23) : 5066 - 5068

← 1 2 3 4 5 →