Addition of Organometallic Nucleophiles (Carbonylmetallates) to the Allyl Ligand of [(η3-C3H5)Pd(μ-Cl)]2. Synthesis and Structure of (η3-C3H5)Mn(CO)3PEt3

被引：0
|
作者：
Kerscher, Thomas [1 ]
Mihan, Shahram [1 ]
Beck, Wolfgang [1 ]
机构：
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2011年 / 66卷 / 08期
关键词：
Allyl; Carbonyl; Palladium; Manganese; X-Ray Structure Determination; METAL-METAL BONDS; CRYSTAL-STRUCTURE; CATIONIC ALLYL; LEWIS-ACIDS; COMPLEXES; MANGANESE; ATTACK; MOLYBDENUM; CHEMISTRY; IRON;
D O I：
10.5560/ZNB.2011.66b0861
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the organometallic nucleophile [Mn(CO)(4)-PEt3](-) at the allyl ligand of [(eta(3)-C3H5)Pd(mu-Cl)](2) proceeds by allyl transfer from Pd(II) to Mn(-I) to give [(eta(3)-C3H5)-Mn(CO)(3)PEt3], of which the structure has been determined by X-ray diffraction.
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收藏
页码：861 / 864
页数：4
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