Effect of textural characteristics on the catalytic performance of supported KCoMoS2 in the synthesis of higher alcohols from syngas

被引:4
|
作者
Osman, Mohamed E. [1 ,2 ]
Maximov, Vladimir V. [1 ]
Dipheko, Tshepo D. [1 ,2 ]
Sheshko, Tatiana F. [2 ]
Cherednichenko, Alexander G. [2 ]
Kogan, Victor M. [1 ]
机构
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
[2] Peoples Friendship Univ Russia RUDN Univ, Moscow 117198, Russia
关键词
syngas; alcohols; alkanols; heterogeneous catalysis; transition metal sulfide catalysts; cobalt compounds; MIXED ALCOHOLS; SYNTHESIS GAS; MOLYBDENUM; CONVERSION; ALKALI;
D O I
10.1016/j.mencom.2022.07.026
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The influence of textural characteristics on the catalytic performance of supported KCoMoS2 catalysts was explored to provide essential information for the design of better catalysts for the synthesis of higher alcohols (C-1-C-5) from syngas. Syngas conversion was carried out over KCoMoS2 catalysts supported on various mesoporous (alumina and carbon-coated alumina) and microporous (two types of powdered activated carbons) materials. The experimental results show that catalysts supported over microporous materials exhibit higher catalytic activity in HAS from syngas than catalysts based on mesoporous materials.
引用
收藏
页码:510 / 513
页数:4
相关论文
共 50 条
  • [21] Effect of Cerium Addition on the Catalytic Performance of Cu-Fe/SiO2 for the Synthesis of Lower Alcohols from Syngas
    Mao Dong-Sen
    Guo Qiang-Sheng
    Yu Jun
    Han Lu-Peng
    Lu Guan-Zhong
    ACTA PHYSICO-CHIMICA SINICA, 2011, 27 (11) : 2639 - 2645
  • [22] Effect of preparation method on performance of Cu-Fe/SiO2 catalysts for higher alcohols synthesis from syngas
    Sun, Chao
    Mao, Dongsen
    Han, Lupeng
    Yu, Jun
    RSC ADVANCES, 2016, 6 (60): : 55233 - 55239
  • [23] The deactivation of Cu-Co alloy nanoparticles supported on ZrO2 for higher alcohols synthesis from syngas
    Liu, Gui-Long
    Niu, Ting
    Cao, Ang
    Geng, Yu-Xia
    Zhang, Yuan
    Liu, Yuan
    FUEL, 2016, 176 : 1 - 10
  • [24] Bimetallic CuCo nanoparticles derived from hydrotalcite supported on carbon fibers for higher alcohols synthesis from syngas
    Wang, Lianfang
    Cao, Ang
    Liu, Guilong
    Zhang, Lihong
    Liu, Yuan
    APPLIED SURFACE SCIENCE, 2016, 360 : 77 - 85
  • [25] The Effect of CO pretreatment on Fe/ADM Catalyst for Higher Alcohols Synthesis from Syngas
    Xiao, Haicheng
    Kong, Fanhua
    Wang, Guizhi
    Wang, Sihan
    Wang, Gang
    Li, Debao
    Li, Wenhuai
    Sun, Yuhan
    RENEWABLE AND SUSTAINABLE ENERGY, PTS 1-7, 2012, 347-353 : 3772 - +
  • [26] Remarkably enhanced catalytic performance of three-dimensional hierarchically porous Mo2C catalysts for higher alcohols synthesis from syngas
    He, Sihui
    Qu, Hao
    Liu, Jiadong
    Sun, Jian
    Su, Yue
    Hu, Ruijue
    Zhang, Yulong
    Su, Haiquan
    MOLECULAR CATALYSIS, 2024, 556
  • [27] Fe modified CuMnZrO2 catalysts for higher alcohols synthesis from syngas:: Effect of calcination temperature
    Xu, R
    Wei, W
    Li, WH
    Hu, TD
    Sun, YH
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 234 (1-2) : 75 - 83
  • [28] Preparation of KNiMo-based catalysts by using non-thermal plasma and their catalytic performance in the synthesis of higher alcohols from syngas
    Li, Ying
    Zhao, Lu
    Liu, Xiao-Zhan
    Zeng, Chun-Xin
    Fang, Ke-Gong
    Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2019, 47 (05): : 513 - 522
  • [29] Effects of gallium as an additive on activated carbon-supported cobalt catalysts for the synthesis of higher alcohols from syngas
    Gao, Shan
    Li, Xiaoyun
    Li, Yuyang
    Yu, Haibin
    Zhang, Fanfan
    Sun, Yanmin
    Fang, Huihuang
    Zhang, Xuebin
    Liang, Xuelian
    Yuan, Youzhu
    FUEL, 2018, 230 : 194 - 201
  • [30] Activated-carbon-supported K-Co-Mo catalysts for synthesis of higher alcohols from syngas
    Lv, Meimei
    Xie, Wei
    Sun, Song
    Wu, Gaimei
    Zheng, Lirong
    Chu, Shengqi
    Gao, Chen
    Bao, Jun
    CATALYSIS SCIENCE & TECHNOLOGY, 2015, 5 (05) : 2925 - 2934