Mixed-Ligand Complexes of Dipropyldithiocarbamatozinc(II) with 1,10-Phenanthroline, 2,2′-Bipyridine, and 4,4′-Bipyridine

被引：0

作者：

Berus, E. I. ^{[1
]}

Zemskova, S. M. ^{[2
]}

Glinskaya, L. A. ^{[2
]}

Klevtsova, R. F. ^{[2
]}

Vasil'ev, A. D. ^{[3
]}

Mazhara, A. P. ^{[2
]}

Larionov, S. V. ^{[2
]}

机构：

[1] Novosibirsk State Univ, Novosibirsk 630090, Russia

[2] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

[3] Russian Acad Sci, Inst Phys, Siberian Div, Novosibirsk, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 1998年 / 43卷 / 11期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixed-ligand complexes of di-n-propyldithiocarbamatozinc(II) with 1,10-phenanthroline, 2,2'-bipyridine, and 4,4'-bipyridine were synthesized. An X-ray diffraction study of the [Zn(n-C(3)H(7))(2)NCS(2)](2)C(12)H(10)N(2) and {Zn[(n-C(3)H(7))(2)NCS(2)](2)}(2)C(10)H(8)N(2) complexes was performed. The structure of the first complex is mononuclear with an octahedral ZnN(2)S(4) coordination core, and the structure of the second complex is binuclear with a tetragonal-pyramidal ZnNS(4) coordination core. It is found that the synthesized complexes are volatile upon heating in vacuum.

引用

页码：1719 / 1722

页数：4

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