First kinetic evidence for the CH/π and π/π solute-solvent interaction of C60 in the Diels-Alder reaction with cyclohexadiene

被引：6
|
作者：
Oshima, Takumi [1 ]
Mikie, Tsubasa [1 ]
Ikuma, Naohiko [1 ]
Yakuma, Hajime [1 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Suita, Osaka, Japan
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 09期
关键词：
HALOFORM INTERCALATED C-60; FACE AROMATIC INTERACTIONS; MOLECULAR TORSION BALANCE; SUPRAMOLECULAR CHEMISTRY; CHEMICAL-REACTIVITY; FULLERENES C-60; SOLID-STATE; SOFT ACIDS; C-70; SOLUBILITY;
D O I：
10.1039/c2ob06748j
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first CH/pi solute-solvent interaction of C-60 was evidenced by the kinetic solvent effects in the Diels-Alder reaction with 1,3-cyclohexadiene based on the evaluation of linear free energy relationship of log k(2) with empirical solvent polarity and basicity parameters, E-T(30) and D-pi, respectively.
引用
收藏
页码：1730 / 1734
页数：5
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