Synthesis and Properties of Naphtho[2,3-e]-1,2-azaphosphorine 2-Oxides: PN-Anthracene Analogues

被引：14

作者：

Takaesu, Noah A. ^{[1
,2
]}

Ohta, Eisuke ^{[1
,2
,4
]}

Zakharov, Lev N. ^{[3
]}

Johnson, Darren W. ^{[1
,2
]}

Haley, Michael M. ^{[1
,2
]}

机构：

[1] Univ Oregon, Dept Chem & Biochem, Eugene, OR 97403 USA

[2] Univ Oregon, Inst Mat Sci, Eugene, OR 97403 USA

[3] Univ Oregon, CAMCOR, Eugene, OR 97403 USA

[4] Osaka Prefecture Univ, Dept Appl Chem, Grad Sch Engn, Naka Ku, 1-1 Gakuen Cho, Sakai, Osaka 5998531, Japan

来源：

ORGANOMETALLICS | 2017年 / 36卷 / 14期

基金：

美国国家科学基金会;

关键词：

HETEROCYCLIC PHOSPHORUS-COMPOUNDS; STEREOCHEMISTRY; CYCLIZATION;

D O I：

10.1021/acs.organomet.7b00281

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the expedient synthesis of a series of new "PN-anthracene" derivatives, the naphtho[2,3-e]-1,2-azaphosphorine-2-oxides, which incorporate a variety of 3-aryl substituents. These compounds represent a new class of pi-extended PN-heterocycles, featuring strong UV absorption, emission in the visible range, and Stokes shifts up to 10000 cm(-1). These molecules show alignment of dipoles, strong dimerization through N-H and P=O hydrogen bond donors/acceptors, and efficient aromatic stacking in the solid state.

引用

页码：2491 / 2493

页数：3

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