Palladium-catalyzed C(sp3)-P(III) bond formation reaction with acylphosphines as phosphorus source

被引：6

作者：

Zhang, Mengyue ^{[1
]}

Ma, Zhichao ^{[1
]}

Du, Hongguang ^{[1
]}

Wang, Zhiqian ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, Coll Chem, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China

来源：

TETRAHEDRON LETTERS | 2020年 / 61卷 / 28期

基金：

中国国家自然科学基金;

关键词：

Pd catalyst; Acylphosphine; C(sp(3))-P(III) bond; Alkyl substituted phosphines; P-STEREOGENIC PHOSPHINES; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC ALKYLATION; LIGANDS; PHOSPHORAMIDITES; BORANES; ACID;

D O I：

10.1016/j.tetlet.2020.152125

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed C(sp(3))-P(III) bond formation reaction for alkyl substituted phosphines preparation was developed. In this reaction, various alkyl bromides and limited alkyl chlorides reacted with acylphosphine under relative mild and easily accessible condition, and differential phosphines were afforded in good yields. This reaction made up the application of palladium catalysis in C(sp(3))-P(III) bond formation, and indicated a practical application of acylphosphine as a phosphination reagent. (C) 2020 Elsevier Ltd. All rights reserved.

引用

页数：4

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