Densities, excess volumes, and partial molar volumes of m-xylene plus ethyl acrylate, plus butyl acrylate, plus methyl methacrylate, and plus styrene at 298.15 K

被引：15

作者：

Peralta, RD ^{[1
]}

Infante, R

Cortez, G

Cadenas, G

Wisniak, J

机构：

[1] Ctr Invest Quim Aplicada, Saltillo 25000, Coahuila, Mexico

[2] Ben Gurion Univ Negev, Dept Chem Engn, IL-84105 Beer Sheva, Israel

来源：

INTERNATIONAL JOURNAL OF THERMOPHYSICS | 2003年 / 24卷 / 04期

关键词：

acrylates; densities; excess volumes; m-xylene; monomers; styrene;

D O I：

10.1023/A:1025057002380

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Densities of the binary systems of m-xylene with ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene have been measured as a function of composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. The excess volumes are positive for the binaries of m-xylene with methyl methacrylate, ethyl acrylate, and styrene. The excess volumes for the m-xylene+ butyl acrylate system are positive for solvent (m-xylene) concentrations below 0.3 mole fraction and negative above this concentration.

引用

页码：1061 / 1071

页数：11

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