Synthesis, characterization, and magnetic properties of rare earth containing Mo4/3RE2/3AlB2 i-MAB phases

被引：4

作者：

Tao, Quanzheng ^{[1
]}

Palisaitis, Justinas ^{[2
]}

Li, Youbing ^{[3
]}

Huang, Qing ^{[3
]}

Persson, Per O. A. ^{[2
]}

Rosen, Johanna ^{[1
]}

机构：

[1] Linkoping Univ, Dept Phys Chem & Biol IFM, Mat Design Div, SE-58183 Linkoping, Sweden

[2] Linkoping Univ, Dept Phys Chem & Biol IFM, Thin Film Phys Div, Linkoping, Sweden

[3] Chinese Acad Sci, Ningbo Inst Ind Technol, Engn Lab Adv Energy Mat, Ningbo, Peoples R China

来源：

MATERIALS RESEARCH LETTERS | 2022年 / 10卷 / 05期

基金：

瑞典研究理事会;

关键词：

Laminated borides; chemical ordering; rare earth elements; magnetic materials; METAL BORIDES;

D O I：

10.1080/21663831.2022.2044929

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Recently, we presented a family of in-plane chemically ordered transition metal borides of the general formula (M-2/3'M-1/3")(2)AlB2. Here, we investigate incorporation of magnetic rare earth (RE) elements into this structure by synthesis and analysis of Mo4/3RE2/3AlB2, where RE = Ho, Tb, and Er. The crystal structure is verified by X-ray diffraction and scanning transmission electron microscopy, while the composition is derived from energy dispersive X-ray analysis. Through magnetization measurements, we also show that Mo4/3Ho2/3AlB2 orders antiferromagnetically below 9 K. We suggest that (M-2/3'M-1/3")(2)AlB2 could potentially be a versatile platform for new magnetic materials, in 3D as well as 2D. [GARPHICS] IMPACT STATEMENT This paper introduces magnetic elements to i-MAB phases family with a formula of Mo4/3RE2/3AlB2 (RE = Ho, Er, and Tb), which opens a venue for further exploration of chemically ordered magnetic materials.

引用

页码：295 / 300

页数：6

共 50 条

[31] Synthesis, characterization and luminescent properties of complexes of rare earth nitrates with 2,2′:4′,4":2",2′′′-quaterpyridine
Tang, Y
Zhang, ZH
Tan, MY
Wang, R
JOURNAL OF RARE EARTHS, 2002, 20 (05) : 388 - 390
[32] Principles of reactions in the synthesis of rare earth fluorides in RE2O3-NH4HF2 systems
Hao, Zhanzhong
Zhang, Jianliang
Wang, Bin
Beijing Keji Daxue Xuebao/Journal of University of Science and Technology Beijing, 2007, 29 (03): : 272 - 277
[33] MAGNETIC-PROPERTIES OF RARE EARTH-2 SE3
BARAKADZE, DG
CHECHERNIKOV, VI
KUZNETSOV, NT
SLOVYANSKIKH, VK
GRACHEVA, NV
INORGANIC MATERIALS, 1987, 23 (12) : 1829 - 1831
[34] Magnetic properties of R(2)CoGa(3) (R=rare earth) compounds
Routsi, CD
Yakinthos, JK
Garnier, A
Gignoux, D
Lionti, F
Schmitt, D
JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 240 (1-2) : 151 - 155
[35] Magnetic properties of lithium-containing rare earth garnets Li3RE3Te2O12 (RE = Y, Pr, Nd, Sm-Lu)
Cevallos, F. Alex
Guo, Shu
Cava, R. J.
MATERIALS RESEARCH EXPRESS, 2018, 5 (12):
[36] Structure and electrical properties of Ln2(MO4)3(Ln = La or Sm; M = W or Mo) nanoceramics
Jayalekshmy, N. L.
John, Annamma
Thomas, Jijimon K.
Solomon, Sam
JOURNAL OF THE AUSTRALIAN CERAMIC SOCIETY, 2023, 59 (04) : 1123 - 1136
[37] RE2(MO4)3:Ln3+ (RE = Y, La, Gd, Lu; M = W, Mo; Ln = Eu, Sm, Dy) microcrystals: controlled synthesis, microstructure and tunable luminescence
Zhou, You
Yan, Bing
CRYSTENGCOMM, 2013, 15 (28): : 5694 - 5702
[38] The crystal structure and magnetic behaviour of the ternary rare earth compounds RE(2)Nb(3)X(4) with RE equivalent to rare earth and X equivalent to Si, Ge
Le Bihan, T
Hiebl, K
Rogl, P
Noel, H
JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 235 (01) : 80 - 83
[39] Magnetic properties and magnetic entropy change in rare earth-rich aluminium compounds of RE2CuAl3 (RE = Dy and Tm)
Wang, Lijuan
Bao, Chenping
Gao, Wenlin
Pang, Yanguo
Wang, Xiangjie
Zhang, Yikun
Cui, Jianzhong
INTERMETALLICS, 2018, 97 : 8 - 11
[40] RAMAN STUDIES ON ROCK-FORMING MINERALS .2. MINERALS CONTAINING MO3, MO4, AND MO6 GROUPS
GRIFFITH, WP
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (02): : 286 - +

← 1 2 3 4 5 →