Indium-Sulfur Supertetrahedral Polymers Integrated with [M(phen)3]2+ Cations (M = Ni and Fe)

被引：31
|
作者：
Zhang, Xu [1 ,2 ]
Luo, Wen [1 ,2 ]
Zhang, Ya-Ping [1 ,2 ]
Jiang, Jian-Bing [1 ,2 ]
Zhu, Qin-Yu [1 ,2 ,3 ]
Dai, Jie [1 ,2 ,3 ]
机构：
[1] Soochow Univ, Dept Chem, Suzhou 215123, Peoples R China
[2] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
INORGANIC CHEMISTRY | 2011年 / 50卷 / 15期
关键词：
SENSITIZED SOLAR-CELLS; HYDROTHERMAL SYNTHESIS; CHALCOGENIDE CLUSTERS; CRYSTAL-STRUCTURES; ELECTRON-TRANSFER; SULFIDE CLUSTERS; BUILDING-BLOCKS; VANADIUM-OXIDES; METAL-COMPLEXES; OPEN FRAMEWORKS;
D O I：
10.1021/ic200157v
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of supertetrahedral polymers of chalcogenometalates (T3 cluster compounds) integrated with M-phen complexes (phen =1,10-phenanthroline; M = Ni, Fe) was prepared by a similar solvothermal technique. Compound [Fe(phen)(3)](4)[H4In20S38]center dot Hphen center dot 3HDMA center dot 8H(2)O (Mp-InS-4) (DMA = dimethylamine) is a 1-D straight chain. Compounds [M(Phen)(3)](4)[In20S37]center dot 6Hphen center dot 4H(2)O (M = Ni, Mp-InS-5; Fe, Mp-InS-6) are the first reported 2-D Tn polymers integrated with complex cations of [M(phen)(3)](2+). Compound (Ni(phen)(3)](4)-[H4In20S38]center dot 2Hphen center dot 2HDMA center dot 3H(2)O (Mp-InS-7) shows a zigzag 1-D structure. We find that the reaction time is an important factor in assembling of the T3 dusters. Prolonging the reaction time seems favorable to the higher condensed phases (from 0-D to 2-D). However, a longer reaction time resulted in the crack of 2-D structure. Integrating M-phen complex cations with the chalcogenido anions can improve absorption of the materials in the visible range due to the charge transfers within the cations or between cations and anions.
引用
收藏
页码：6972 / 6978
页数：7
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