Surface Roughness Influence on CPE Parameters in Electrolytic Cells

被引：17

作者：

Vieira, Denner S. ^{[1
]}

Fernandes, Paulo R. G. ^{[1
,2
]}

Mukai, Hatsumi ^{[1
,2
]}

Zola, Rafael S. ^{[1
,3
]}

Lenzi, Giane Goncalves ^{[4
]}

Lenzi, Ervin K. ^{[5
]}

机构：

[1] Univ Estadual Maringa, Dept Fis, Ave Colombo 5790, BR-87020900 Maringa, Parana, Brazil

[2] CNPq, Natl Inst Sci & Technol Complex Fluids, BR-05508090 Sao Paulo, SP, Brazil

[3] Univ Tecnol Fed Parana, Dept Fis, R Marcilio Dias 635, BR-86812460 Apucarana, PR, Brazil

[4] Univ Tecnol Fed Parana, Dept Engn Quim, Ave Monteiro Lobato, BR-84016210 Ponta Grossa, PR, Brazil

[5] Univ Estadual Ponta Grossa, Dept Fis, Ave Gen Carlos Cavalcanti 4748, BR-84030900 Ponta Grossa, PR, Brazil

来源：

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2016年 / 11卷 / 09期

关键词：

Electrical Impedance; CPE; Surface roughness; PNP; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; SENSITIZED SOLAR-CELLS; ELEMENT; LIQUID; BEHAVIOR; DISTRIBUTIONS; CAPACITANCE; ELECTRODES; INTERFACE; MECHANISM;

D O I：

10.20964/2016.09.56

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

We investigate how the changes on the electrode surface may influence the behavior of the constant-phase elements (CPE) and, consequently, electrical response of an electrolytic cell. This analysis is performed by using an experiment with Milli- Q water and stainless steel electrodes with three different types of polishment: smooth, fine sandpaper, and rough sandpaper. The experimental data is obtained from an Electrical Impedance Spectroscopy (EIS) measure and analyzed by means of an equivalent circuit with CPE elements.

引用

页码：7775 / 7784

页数：10

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