Direct C-H Bond Borylation of (Hetero)Arenes: Evolution from Noble Metal to Metal Free

被引：62
|
作者：
Li, Yahui [1 ]
Wu, Xiao-Feng [2 ,3 ]
机构：
[1] Anhui Agr Univ, Sch Resources & Environm, Key Lab Agrifood Safety Anhui Prov, Hefei 230036, Anhui, Peoples R China
[2] Zhejiang Sci Tech Univ Xiasha Campus, Dept Chem, Hangzhou 310018, Zhejiang, Peoples R China
[3] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 05期
关键词：
homogeneous catalysis; C-H bond borylation; organoboron compounds; pinacol boronate esters; ARENES; FUNCTIONALIZATION; ACTIVATION; COMPLEXES; CHEMISTRY; INDOLES;
D O I：
10.1002/anie.201914914
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Organoboron compounds are among the most versatile and useful building blocks in modern synthetic chemistry. The past decades have seen impressive developments in the direct C-H bond borylation of (hetero)arenes in which the applied catalysts are shifting from noble metals to metal-free systems. This Highlight gives a brief summary on this evolution and focuses on recent elegant work in this field.
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收藏
页码：1770 / 1774
页数：5
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