Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by C-H Bond Cleavage

被引：2504
|
作者：
Ackermann, Lutz [1 ]
Vicente, Ruben [1 ]
Kapdi, Anant R. [1 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 52期
关键词：
arylation; biaryls; C-H functionalization; homogeneous catalysis; transition metals; CROSS-COUPLING REACTIONS; INTRAMOLECULAR DIRECT ARYLATION; DIRECT C-2 ARYLATION; INCLUDING FREE (NH)-IMIDAZOLE; PROTON-ABSTRACTION MECHANISM; PALLADIUM-PROMOTED SYNTHESIS; MEDIATED DIRECT ARYLATION; ONE-POT SYNTHESIS; ARYL CHLORIDES; REGIOSELECTIVE ARYLATION;
D O I：
10.1002/anie.200902996
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(figure represented) Cutting across: Direct arylations are increasingly viable alternatives to conventional cross-coupling reactions with stoichiometric amounts of organometallic reagents (see Scheme). This Review summarizes recent progress in the rapidly evolving research area of transition-metalcatalyzed C-H bond-cleavage reactions for (hetero)aryl syntheses. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：9792 / 9826
页数：35
相关论文
共 50 条
  • [1] Transition-Metal-Catalyzed Direct C-H Alkenylation, Alkynylation, Benzylation, and Alkylation of (Hetero)arenes
    Messaoudi, Samir
    Brion, Jean-Daniel
    Alami, Mouad
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (34) : 6495 - 6516
  • [2] Sustainable protocols for direct C-H bond arylation of (hetero)arenes
    Albano, Gianluigi
    Punzi, Angela
    Capozzi, Maria Annunziata M.
    Farinola, Gianluca M.
    GREEN CHEMISTRY, 2022, 24 (05) : 1809 - 1894
  • [3] Direct C-H Bond Arylation of (Hetero)arenes with Aryl and Heteroarylboronic Acids
    Guchhait, Sankar K.
    Kashyap, Maneesh
    Saraf, Shuddham
    SYNTHESIS-STUTTGART, 2010, (07): : 1166 - 1170
  • [4] Transition-metal-catalyzed direct arylations via C-H bond cleavages
    Ackermann, Lutz
    PURE AND APPLIED CHEMISTRY, 2010, 82 (07) : 1403 - 1413
  • [5] Transition-Metal-Catalyzed Arylation of 1-Deazapurines via C-H Bond Activation
    Iaroshenko, Viktor O.
    Ali, Iftikhar
    Mkrtchyan, Satenik
    Semeniuchenko, Volodymyr
    Ostrovskyi, Dmytro
    Langer, Peter
    SYNLETT, 2012, (18) : 2603 - 2608
  • [6] Transition metal-catalyzed olefin arylation via C-H bond activation of arenes
    Matsumoto, Takaya
    CATALYSIS SURVEYS FROM ASIA, 2007, 11 (1-2) : 31 - 48
  • [7] Mild Rh(III)-Catalyzed Direct C-H Bond Arylation of (Hetero)Arenes with Arylsilanes in Aqueous Media
    Lu, Ming-Zhu
    Lu, Ping
    Xu, Yun-He
    Loh, Teck-Peng
    ORGANIC LETTERS, 2014, 16 (10) : 2614 - 2617
  • [8] Transition-Metal-Catalyzed C-H Arylation Using Organoboron Reagents
    Basak, Sumon
    Biswas, Jyoti Prasad
    Maiti, Debabrata
    SYNTHESIS-STUTTGART, 2021, 53 (18): : 3151 - 3179
  • [9] Recent Advances on Transition-Metal-Catalyzed Asymmetric C-H Arylation Reactions
    Li, Mingliang
    Wang, Jun
    SYNTHESIS-STUTTGART, 2022, 54 (21): : 4734 - 4752
  • [10] Rhodium-Catalyzed C-H Bond Arylation of Arenes
    Bouffard, Jean
    Itami, Kenichiro
    C-H ACTIVATION, 2010, 292 : 231 - 280
12345