A silver(I) coordination polymer luminescent thermometer

被引：21
|
作者：
He, Yuan-Chun [1 ]
Xu, Na [1 ]
Zheng, Xiaofeng [1 ]
Yu, Yang [1 ]
Ling, Baoping [1 ]
You, Jinmao [1 ]
机构：
[1] Qufu Normal Univ, Coll Chem & Chem Engn, Qufu 273165, Peoples R China
来源：
DYES AND PIGMENTS | 2017年 / 136卷
基金：
中国国家自然科学基金;
关键词：
Coordination polymer; Silver; Crystal structure; Luminescent thermometer; Ag ... Ag interaction; METAL-ORGANIC FRAMEWORK; SINGLE-CRYSTAL TRANSFORMATION; ACID SYNTHESES; PHOTOLUMINESCENT PROPERTIES; HIGH-SENSITIVITY; MOF; SERIES; COMPLEXES; TOPOLOGY; IONS;
D O I：
10.1016/j.dyepig.2016.09.021
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A novel coordination polymer, namely, [Ag-0.5(H2O)][Ag-1.5(L)(H2O)].2H(2)O (1) (H2L = 4'-((2-carboxyphenoxy)methyl)bipheny1-2-carboxylic acid) has been successfully synthesized at room temperature. In compound 1, L anions bridge Ag(I) cations to form a one dimensional (1D) double chain structure, while there is an infinite Ag(I) chain joined by argentophilic interaction. Neighboring double chains are further extend into two dimensional (2D) supramolecular layers via intermolecular hydrogen bonding interactions. Compound 1 has been characterized by infrared spectrum (IR), elemental analysis and powder X-ray diffraction (PXRD) analysis, and the luminescent properties of 1 were measured in detail. The luminescent intensity decreases regularly along with temperature increasing, which displays that compound 1 is a potential luminescent thermometer. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：577 / 582
页数：6
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