Tetranuclear bismuth complex Bi4(O)2(O2CC6H2F3-3,4,5,)8•2η6-C6H5Me:: Synthesis and structure

被引：5
|
作者：
Sharutin, VV
Egorova, IV
Sharutina, OK
Ivanenko, TK
Adonin, NY
Starichenko, VF
Pushilin, MA
Gerasimenko, AV
机构：
[1] Blagoveshchensk State Pedag Univ, Blagoveshchensk 675000, Russia
[2] Russian Acad Sci, Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia
[3] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 29卷 / 12期
关键词：
D O I：
10.1023/B:RUCO.0000008395.98029.6c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tetranuclear organobismuth complex Bi-4(O)(2)(O2CC6H2F3-3,4,5)(8) . 2eta(6)-C6H5Me with four bismuth atoms joined via the bridging carboxylate ligands and oxygen atoms was studied using X-ray diffraction analysis. The coordination sphere of either of the two terminal bismuth atoms contains the chelate carboxylate ligand and the toluene molecule. For the bridging tricoordinated oxygen atoms, the Bi-O distances are 2.083(2), 2.119(2), and 2.276(2) Angstrom. The average distance between the bismuth atom and the center of toluene molecule is equal to 3.131 Angstrom.
引用
收藏
页码：838 / 844
页数：7
相关论文
共 50 条
  • [21] Synthesis, properties and crystal structure of a new bismuth oxalate:: Na(C5NH6)[Bi(H2O)(C2O4)2]2•4H2O
    Chen Xin-Xiang
    Cao Yan-Ning
    Zhang Han-Hui
    Chen Yi-Ping
    Chen Xue-Huan
    Chai Xiao-Chuan
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (07) : 865 - 870
  • [22] Synthesis and crystal structure of [Tb4(H2O)2](C2O4)2(C5H6O4)4
    Thomas, P
    Trombe, JC
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2000, 30 (10) : 633 - 639
  • [23] Synthesis and crystal structure of [Tb4(H2O)2](C2O4)2(C5H6O4)4
    P. Thomas
    J.C. Trombe
    Journal of Chemical Crystallography, 2000, 30 : 633 - 639
  • [24] Synthesis and crystal structure of [o-C2H5C6H4NH3]4P4O12•2H2O
    Hemissi, H
    Abid, S
    Rzaigui, M
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2006, 181 (03) : 543 - 551
  • [25] Synthesis and molecular structure of the trinuclear ruthenium cluster cations [H3Ru3{C6H5(CH2)2OC(O)C6H5}(C6Me6)2(O)]+ and [H3Ru3{C6H5(CH2)2OC(O)(CH2)3C6H5}(C6Me6)2(O)]+
    Vieille-Petit, L
    Therrien, B
    Süss-Fink, G
    INORGANICA CHIMICA ACTA, 2004, 357 (12) : 3437 - 3442
  • [26] Synthesis,PropertiesandCrystalStructureofaNewBismuthOxalate:Na（C5NH6）[Bi（H2O）(C2O4)2]2·4H2O
    陈新香
    曹彦宁
    张汉辉
    陈义平
    陈雪焕
    柴小川
    结构化学, 2008, (07) : 865 - 870
  • [27] Synthesis and crystal structure of Zn[(C6H5N3)4(H2O)2](ClO4)2 and Cu[(C6H5N3)4(H2O)2](CIO4)2
    Li, LX
    Wang, XQ
    Shen, GQ
    Wang, RJ
    Shen, DZ
    INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (07) : 453 - 457
  • [28] SYNTHESIS AND STRUCTURE OF TETRANUCLEAR MOLYBDENUM CLUSTER COMPOUND[Mo4S4（μ-O2CC6H5）2（dtp）4]
    Hong Hui ZHUANG Ding Ming WU Jian Quan HUANG Jin Ling HUANG Fuzhou Laboratory of Structure Chemistry and Fujian Institute of Research on the Structure of Matter
    Chinese Chemical Letters, 1991, (07) : 553 - 554
  • [29] Synthesis and crystal structures of [UO2(C6H4NO2)2(C6H5NO2)] and [UO2SO4(C6H5NO2)(H2O)] · H2O
    E. V. Grechishnikova
    E. V. Peresypkina
    A. V. Virovets
    Yu.l N. Mikhailov
    L. B. Serezhkina
    Russian Journal of Coordination Chemistry, 2007, 33 : 458 - 465
  • [30] Synthesis and crystal structures of [UO2(C6H4NO2)2(C6H5NO2)] and [UO2SO4(C6H5NO2)(H2O)] • H2O
    Grechishnikova, E. V.
    Peresypkina, E. V.
    Virovets, A. V.
    Mikhailov, Yu. I. N.
    Serezhkina, L. B.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2007, 33 (06) : 458 - 465
12345