Tetranuclear bismuth complex Bi4(O)2(O2CC6H2F3-3,4,5,)8•2η6-C6H5Me:: Synthesis and structure

被引：5
|
作者：
Sharutin, VV
Egorova, IV
Sharutina, OK
Ivanenko, TK
Adonin, NY
Starichenko, VF
Pushilin, MA
Gerasimenko, AV
机构：
[1] Blagoveshchensk State Pedag Univ, Blagoveshchensk 675000, Russia
[2] Russian Acad Sci, Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia
[3] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 29卷 / 12期
关键词：
D O I：
10.1023/B:RUCO.0000008395.98029.6c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tetranuclear organobismuth complex Bi-4(O)(2)(O2CC6H2F3-3,4,5)(8) . 2eta(6)-C6H5Me with four bismuth atoms joined via the bridging carboxylate ligands and oxygen atoms was studied using X-ray diffraction analysis. The coordination sphere of either of the two terminal bismuth atoms contains the chelate carboxylate ligand and the toluene molecule. For the bridging tricoordinated oxygen atoms, the Bi-O distances are 2.083(2), 2.119(2), and 2.276(2) Angstrom. The average distance between the bismuth atom and the center of toluene molecule is equal to 3.131 Angstrom.
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收藏
页码：838 / 844
页数：7
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