Self-assembled monolayers of clamped oligo(phenylene-ethynylene-butadiynylene)s

被引：16

作者：

Jester, Stefan-S. ^{[1
]}

Schmitz, Daniela ^{[1
]}

Eberhagen, Friederike ^{[1
]}

Hoeger, Sigurd ^{[1
]}

机构：

[1] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 31期

关键词：

SHAPE-PERSISTENT MACROCYCLES; DERIVATIVES; INTERFACE;

D O I：

10.1039/c1cc12435h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rigid rod oligo(phenylene-ethynylene-butadiynylene)s (oPEBs), "half-rings'' of two rigid rods connected via a molecular clamp unit, and shape-persistent macrocycles (cyclic "half-ring dimers'') are synthesized and their self-assembled monolayers (SAMs) are investigated by scanning tunneling microscopy (STM) at the interface of 1,2,4-trichlorobenzene (TCB)/highly oriented pyrolytic graphite (HOPG). The results are important for the design of molecular building blocks for two-dimensional nanoscale architectures on solid surfaces.

引用

页码：8838 / 8840

页数：3

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