Relation of chlorine, copper and sulphur to dioxin emission factors

Dioxin emission factors for different combustion categories range over five orders of magnitude. Both chlorine (Cl-2) and transition metals, including copper (Cu) have been suggested to promote the formation of dioxin in incinerators, and sulphur (S) has been suggested to inhibit dioxin formation. We show that dioxin (PCDD and PCDF) emission factors from 17 different combustion categories are approximately linearly correlated with the average copper or chlorine content of the combusted material, and inverse linearly correlated with the average sulphur content of the material. Copper and chlorine are correlated and, thus cannot be distinguished. The analysis suggests that the wide range of dioxin emission factors could be explained by the content of sulphur and transition metals or chlorine in combusted materials. (C) 2007 Elsevier B.V. All rights reserved.