Cycloaddition of diazoacetates to C60 fullerene catalysed by Pd complexes

被引：6
|
作者：
Tuktarov, A. R. [1 ]
Akhmetov, A. R. [1 ]
Khasanova, L. L. [1 ]
Khalilov, L. M. [1 ]
Dzhemilev, U. M. [1 ]
机构：
[1] Russian Acad Sci, Inst Petr Chem & Catalysis, Ufa 450075, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2010年 / 59卷 / 10期
关键词：
metallocomplex catalysis; C-60; fullerene; diazoacetates; cycloaddition; DERIVATIVES; METHANOFULLERENE;
D O I：
10.1007/s11172-010-0339-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient catalytic method of the cycloaddition to C-60 fullerene of the diazoacetates, containing substituents of diverse structures in ester groups, in the presence of a Pd-based three-component catalyst was developed. An influence of nature and the structure of substituent in the ester group on the activity of diazoacetates in the reaction with C-60 was studied. Yields of respective cycloadducts were determined.
引用
收藏
页码：1959 / 1963
页数：5
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