Thermodynamics of the sorption of organic compounds on polyethylene glycol 400-permethylated β-cyclodextrin stationary phase and its enantioselectivity in gas chromatography

被引：0

作者：

Kuraeva, Yu. G. ^{[1
]}

Onuchak, L. A. ^{[1
]}

Evdokimova, M. A. ^{[1
]}

机构：

[1] Samara State Univ, Samara 443086, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2016年 / 90卷 / 08期

关键词：

gas-liquid chromatography; polyethylene glycol 400; permethylated beta-cyclodextrin; thermodynamics of sorption; enantioselectivity; ALPHA-CYCLODEXTRIN; MONOTERPENOIDS; SEPARATION; ABILITY;

D O I：

10.1134/S0036024416080136

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The thermodynamic characteristics of sorption of 24 organic compounds of various classes from the gas phase on the binary stationary phase based on polyethylene glycol 400 and permethylated beta-cyclodextrin were determined. The influence of geometrical structure and optical activity of organic compounds on the possibility of forming sorbate-macrocycle complexes was examined. It was found that the studied stationary phase shows the enantioselectivity towards low-polar terpenes under the conditions of gas chromatography.

引用

页码：1698 / 1701

页数：4

共 35 条

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