Thermodynamics of the sorption of organic compounds on polyethylene glycol 400-permethylated β-cyclodextrin stationary phase and its enantioselectivity in gas chromatography

被引：0

作者：

Kuraeva, Yu. G. ^{[1
]}

Onuchak, L. A. ^{[1
]}

Evdokimova, M. A. ^{[1
]}

机构：

[1] Samara State Univ, Samara 443086, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2016年 / 90卷 / 08期

关键词：

gas-liquid chromatography; polyethylene glycol 400; permethylated beta-cyclodextrin; thermodynamics of sorption; enantioselectivity; ALPHA-CYCLODEXTRIN; MONOTERPENOIDS; SEPARATION; ABILITY;

D O I：

10.1134/S0036024416080136

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The thermodynamic characteristics of sorption of 24 organic compounds of various classes from the gas phase on the binary stationary phase based on polyethylene glycol 400 and permethylated beta-cyclodextrin were determined. The influence of geometrical structure and optical activity of organic compounds on the possibility of forming sorbate-macrocycle complexes was examined. It was found that the studied stationary phase shows the enantioselectivity towards low-polar terpenes under the conditions of gas chromatography.

引用

页码：1698 / 1701

页数：4

共 35 条

[1] Thermodynamics of the sorption of organic compounds on polyethylene glycol 400–permethylated β-cyclodextrin stationary phase and its enantioselectivity in gas chromatography
Yu. G. Kuraeva
L. A. Onuchak
M. A. Evdokimova
Russian Journal of Physical Chemistry A, 2016, 90 : 1698 - 1701
[2] Thermodynamics of the adsorption of volatile organic compounds in a binary polydimethylsiloxane-permethylated β-cyclodextrin stationary phase, as measured by gas chromatography
Onuchak, L. A.
Platonov, V. I.
Kuraeva, Yu. G.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 87 (05) : 861 - 864
[3] Thermodynamics of the adsorption of volatile organic compounds in a binary polydimethylsiloxane-permethylated β-cyclodextrin stationary phase, as measured by gas chromatography
L. A. Onuchak
V. I. Platonov
Yu. G. Kuraeva
Russian Journal of Physical Chemistry A, 2013, 87 : 861 - 864
[4] PERMETHYLATED BETA-CYCLODEXTRIN AS STATIONARY PHASE IN CAPILLARY GAS-CHROMATOGRAPHY
JUVANCZ, Z
ALEXANDER, G
SZEJTLI, J
JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY & CHROMATOGRAPHY COMMUNICATIONS, 1987, 10 (02): : 105 - 107
[5] Permethylated β-cyclodextrin in liquid poly(oxyethylene) as a stationary phase for capillary gas chromatography
Osorio Grisales, Jaiver
Lebed, Pablo J.
Keunchkarian, Sonia
Gonzalez, Francisco R.
Castells, Cecilia B.
JOURNAL OF CHROMATOGRAPHY A, 2009, 1216 (40) : 6844 - 6851
[6] GAS-PHASE CHROMATOGRAPHY - DESCRIPTION OF NEW STATIONARY PHASE WHOSE SOLVENT IS POLYETHYLENE-GLYCOL WITH MOLAR MASS OF 400
GRANGER, R
GUERMOUC.MH
BENDIAB, SAT
MONTHEAR.JP
VERGNAUD, JM
COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1973, 277 (22): : 1191 - 1194
[7] Gas chromatography-mass spectrometry resolution of sugar acid enantiomers on a permethylated β-cyclodextrin stationary phase
Cooper, George
Sant, Minakshi
Asiyo, Cynthia
JOURNAL OF CHROMATOGRAPHY A, 2009, 1216 (40) : 6838 - 6843
[8] Gas-chromatographic studies of the sorption thermodynamics of adamantanes on a carbon adsorbent modified with polyethylene glycol with β-cyclodextrin additives
Yashkin, S. N.
Ageeva, Yu. A.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 87 (11) : 1921 - 1928
[9] Gas-chromatographic studies of the sorption thermodynamics of adamantanes on a carbon adsorbent modified with polyethylene glycol with β-cyclodextrin additives
S. N. Yashkin
Yu. A. Ageeva
Russian Journal of Physical Chemistry A, 2013, 87 : 1921 - 1928
[10] Thermodynamics of Sorption of Organic Compounds by Sorbents Based on Supramolecular Liquid Crystal HPFAB and β-Cyclodextrin Derivatives under Gas Chromatography Conditions
Kuraeva, Yu. G.
Tugareva, D. A.
Onuchak, L. A.
Kapralova, T. S.
PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2023, 59 (06) : 1104 - 1112

← 1 2 3 4 →