Enantiospecific formation of a three-component helical structure by spontaneous self-assembly

被引：11
|
作者：
Yue, WM [1 ]
Bishop, R [1 ]
Scudder, ML [1 ]
Craig, DC [1 ]
机构：
[1] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia
来源：
CHEMISTRY LETTERS | 1998年 / 08期
关键词：
D O I：
10.1246/cl.1998.803
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A toluene solution of the two racemic helical tubulands 1 and 2 yields crystals of the stoichiometric product 1.2(2).toluene through molecular self-assembly involving simultaneous self-resolution of both diols. This composite helical tubulate structure contains parallel tubes with cross-sectional areas of 22.5 Angstrom(2).
引用
收藏
页码：803 / 804
页数：2
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