Accessible protocol for asymmetric hydroformylation of vinylarenes using formaldehyde

被引：28

作者：

Morimoto, Tsumoru ^{[1
]}

Fujii, Tetsuji ^{[1
]}

Miyoshi, Kota ^{[1
]}

Makado, Gouki ^{[1
]}

Tanimoto, Hiroki ^{[1
]}

Nishiyama, Yasuhiro ^{[1
]}

Kakiuchi, Kiyomi ^{[1
]}

机构：

[1] Nara Inst Sci & Technol NAIST, Grad Sch Mat Sci, Nara, Japan

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2015年 / 13卷 / 16期

关键词：

CATALYZED HYDROFORMYLATION; ENANTIOSELECTIVE HYDROFORMYLATION; RHODIUM; OLEFINS; LIGANDS; CARBONYLATION; ALDEHYDES; ALKENES;

D O I：

10.1039/c5ob00378d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report herein on an accessible protocol for the asymmetric hydroformylation of vinylarenes using formaldehyde as a substitute for syngas. The regioselectivity (branched/linear = up to 96/4) and enantioselectivity (up to 95% ee) can be attributed to the use of chiral Ph-bpe as a ligand.

引用

页码：4632 / 4636

页数：5

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