Accessible protocol for asymmetric hydroformylation of vinylarenes using formaldehyde

被引：28

作者：

Morimoto, Tsumoru ^{[1
]}

Fujii, Tetsuji ^{[1
]}

Miyoshi, Kota ^{[1
]}

Makado, Gouki ^{[1
]}

Tanimoto, Hiroki ^{[1
]}

Nishiyama, Yasuhiro ^{[1
]}

Kakiuchi, Kiyomi ^{[1
]}

机构：

[1] Nara Inst Sci & Technol NAIST, Grad Sch Mat Sci, Nara, Japan

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2015年 / 13卷 / 16期

关键词：

CATALYZED HYDROFORMYLATION; ENANTIOSELECTIVE HYDROFORMYLATION; RHODIUM; OLEFINS; LIGANDS; CARBONYLATION; ALDEHYDES; ALKENES;

D O I：

10.1039/c5ob00378d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report herein on an accessible protocol for the asymmetric hydroformylation of vinylarenes using formaldehyde as a substitute for syngas. The regioselectivity (branched/linear = up to 96/4) and enantioselectivity (up to 95% ee) can be attributed to the use of chiral Ph-bpe as a ligand.

引用

页码：4632 / 4636

页数：5

共 50 条

[1] Easily Accessible TADDOL-Derived Bisphosphonite Ligands: Synthesis and Application in the Asymmetric Hydroformylation of Vinylarenes
Allmendinger, Simon
Kinuta, Hirotaka
Breit, Bernhard
ADVANCED SYNTHESIS & CATALYSIS, 2015, 357 (01) : 41 - 45
[2] Asymmetric hydroformylation of vinylarenes with rhodium diphosphite catalyst
Uriz, P
Fernández, E
Ruiz, N
Claver, C
INORGANIC CHEMISTRY COMMUNICATIONS, 2000, 3 (10) : 515 - 519
[3] Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring
Freixa, Z
Bayón, JC
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (14): : 2067 - 2068
[4] Asymmetric Hydroformylation Using Rhodium
Cunillera, Anton
Godard, Cyril
Ruiz, Aurora
RHODIUM CATALYSIS, 2018, 61 : 99 - 143
[5] HYDROFORMYLATION OF FORMALDEHYDE
ROTH, JA
ORCHIN, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 172 (02) : C27 - C28
[6] Rhodium-catalysed asymmetric hydroformylation of vinylarenes with chiral P,N-ligands based on DIOP skeleton
Aghmiz, A
Masdeu-Bultó, AM
Claver, C
Sinou, D
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 184 (1-2) : 111 - 119
[7] ASYMMETRIC OLEFINS HYDROFORMYLATION .6. ASYMMETRIC HYDROFORMYLATION OF ISOMERIC BUTENES USING PLATINUM CATALYSTS
CONSIGLIO, G
PINO, P
HELVETICA CHIMICA ACTA, 1976, 59 (02) : 642 - 645
[8] Asymmetric acylarylation of vinylarenes with aldehydes
Li, Zhiheng
Chen, Si-Cong
Xing, Dong
TRENDS IN CHEMISTRY, 2025, 7 (03): : 163 - 164
[9] Easily Accessible and Highly Tunable Bisphosphine Ligands for Asymmetric Hydroformylation of Terminal and Internal Alkenes
Xu, Kun
Zheng, Xin
Wang, Zhiyong
Zhang, Xumu
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (15) : 4357 - 4362
[10] ELECTRONIC EFFECT OF RH-PHOSPHINE CATALYSTS FOR THE HYDROFORMYLATION OF VINYLARENES
CHAN, ASC
PAI, CC
CHEN, SM
YANG, TK
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 178 - INOR

← 1 2 3 4 5 →