Selective hydrogenation of α-pinene to cis-pinane over Ru nanocatalysts in aqueous micellar nanoreactors

被引：19

作者：

Hou, Shengli ^{[1
]}

Xie, Congxia ^{[1
]}

Yu, Fengli ^{[1
]}

Yuan, Bing ^{[1
]}

Yu, Shitao ^{[2
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China

[2] Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China

来源：

RSC ADVANCES | 2016年 / 6卷 / 60期

基金：

中国国家自然科学基金;

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; PD NANOPARTICLES; BIPHASIC SYSTEM; METAL-CATALYSTS; WATER; COUPLINGS; HYDROFORMYLATION; AMPHIPHILE; COMPLEXES; ARENES;

D O I：

10.1039/c6ra13099b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

D-alpha-Tocopheryl polyethylene glycol 1000 succinate (TPGS-1000) stabilized Ru(0) nanoparticles were prepared and characterized. These nanoparticles were employed to selectively hydrogenate alpha-pinene to cis-pinane. With a small amount of Na2CO3 present, reaction rates could be increased significantly, and the reaction medium could be readily recycled. TEM, CLSM, IR and leaching experiments were employed to quantify the advantages of the catalytic system. The procedure is environmentally friendly. It offers a reference for the catalytic hydrogenation of other hydrophobic natural products.

引用

页码：54806 / 54811

页数：6

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