Fluorescence and visual detection of fluoride ions using a photoluminescent graphene oxide paper sensor

被引:77
|
作者
Chen, Xiaochun [1 ,2 ]
Yu, Shaoming [1 ,2 ]
Yang, Liang [3 ]
Wang, Jianping [3 ]
Jiang, Changlong [3 ,4 ,5 ]
机构
[1] Hefei Univ Technol, Sch Chem & Chem Engn, Hefei 230009, Anhui, Peoples R China
[2] Anhui Key Lab Controllable Chem React & Mat Chem, Hefei 230009, Anhui, Peoples R China
[3] Chinese Acad Sci, Inst Intelligent Machines, Hefei 230031, Anhui, Peoples R China
[4] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
[5] Chinese Acad Sci, State Key Lab Transducer Technol, Hefei 230031, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
QUANTUM DOTS; TURN-ON; FRET; NANOPARTICLES; HYBRID; ANION; PROBE; CHEMISTRY; BRIGHT;
D O I
10.1039/c6nr02878k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The instant and on-site detection of trace aqueous fluoride ions is still a challenge for environmental monitoring and protection. This work demonstrates a new analytical method and its utility of a paper sensor for visual detection of F- on the basis of the fluorescence resonance energy transfer (FRET) between photoluminescent graphene oxide (GO) and silver nanoparticles (AgNPs) through the formation of cyclic esters between phenylborinic acid and diol. The fluorescence of GO was quenched by the AgNPs, and trace F- can recover the fluorescence of the quenched photoluminescent GO. The increase in fluorescence intensity is proportional to the concentration of F- in the range of 0.05-0.55 nM, along with a limit of detection (LOD) as low as 9.07 pM. Following the sensing mechanism, a paper-based sensor for the visual detection of aqueous F- has been successfully developed. The paper sensor showed high sensitivity for aqueous F-, and the LOD could reach as low as 0.1 mu M as observed by the naked eye. The very simple and effective strategy reported here could be extended to the visual detection of a wide range of analytes in the environment by the construction of highly efficient FRET nanoprobes.
引用
收藏
页码:13669 / 13677
页数:9
相关论文
共 50 条
  • [31] Removal of fluoride ions using calcined paper sludge
    Wajima, Takaaki
    Rakovan, John F.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2013, 113 (03) : 1027 - 1035
  • [32] Removal of fluoride ions using calcined paper sludge
    Takaaki Wajima
    John F. Rakovan
    Journal of Thermal Analysis and Calorimetry, 2013, 113 : 1027 - 1035
  • [33] A ligand-free hydrogel as a visual fluorescence sensor for detection of rare-earth ions
    Zhang, Yanan
    Lin, Lin
    Wu, Yingzhen
    Gong, Chenglin
    Feng, Zhuohong
    Wang, Zhezhe
    Huang, Yantang
    Zheng, Zhiqiang
    OPTICS COMMUNICATIONS, 2024, 570
  • [34] Fluorescence sensor for mercury ions in aqueous mediums based on reduced graphene oxide linked with molybdenum disulfide
    Kumar, Anjan
    Ahmad, Nafis
    Jadeja, Yashwantsinh
    Ganesan, Subbulakshmi
    Abd Hamid, Junainah
    Singh, Priyanka
    Kaur, Kiranjeet
    Jaseem, Leeth hassen
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2025, 196
  • [35] Fluorescence Probes Based on Aminoboranes for the Detection of Fluoride Ions and Nitroaromatics: A Bifunctional Fluorescence Detection Platform
    Li, Ruohan
    Chen, Zhiyuan
    Hu, Lai
    Miao, Jinxing
    Zhu, Senqiang
    Liu, Rui
    Zhu, Hongjun
    LUMINESCENCE, 2025, 40 (04)
  • [36] Near-Infrared Colorimetric and Ratiometric Fluorescence Sensor for Fluoride Ions
    Dai, Hui
    Yang, Jinglian
    Ye, Zijian
    Liu, Cong
    Xu, Bingjia
    Shi, Guang
    Su, Shichen
    Zhang, Yujian
    Chi, Zhenguo
    CHEMISTRYSELECT, 2022, 7 (26):
  • [37] Neurotransmitters detection using a fluorescence-based sensor with graphene quantum dots
    Baluta, Sylwia
    Cabaj, Joanna
    Malecha, Karol
    OPTICA APPLICATA, 2017, 47 (02) : 225 - 231
  • [38] Stacked graphene nanoplatelet paper sensor for protein detection
    Heldt, Caryn L.
    Sieloff, Amy K.
    Merillat, Joshua P.
    Minerick, Adrienne R.
    King, Julia A.
    Perger, Warren F.
    Fukushima, Hiroyuki
    Narendra, Jeffri
    SENSORS AND ACTUATORS B-CHEMICAL, 2013, 181 : 92 - 98
  • [39] A fluorescence visual detection for glyphosine based on a biomass carbon quantum dot paper-based sensor
    Wang, Xiaoyan
    Lv, Yiju
    Kong, Xiangfei
    Ding, Zhiyuan
    Cheng, Xia
    Liu, Zheng
    Han, Guo-Cheng
    NEW JOURNAL OF CHEMISTRY, 2023, 47 (22) : 10696 - 10705
  • [40] A colorimetric paper sensor for visual detection of mercury ions constructed with dual-emission carbon dots
    Wang, Yifan
    Yang, Liang
    Liu, Bianhua
    Yu, Shaoming
    Jiang, Changlong
    NEW JOURNAL OF CHEMISTRY, 2018, 42 (19) : 15671 - 15677