Preparation and Crystal Structure of 15α-Hydroxyl-oleanolic Acid

被引：0

作者：

Sun Hua ^{[1
]}

Liu Ting ^{[1
]}

Shen Yan-Jun ^{[1
]}

Zhang Li-Ming ^{[1
]}

Wang Min ^{[1
]}

机构：

[1] Tianjin Univ Sci & Technol, Coll Biotechnol, Minist Educ, Key Lab Ind Microbiol, Tianjin 300457, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 29卷 / 12期

关键词：

crystal structure; oleanolic acid; 15 alpha-hydroxyl-oleanolic acid; biotransformation; URSOLIC ACID; TRITERPENOIDS; DERIVATIVES;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound 15 alpha-hydroxyl-oleanolic acid was biotransformed from oleanolic acid with Colletotrichum lini AS3 4486, and its structure was characterized by H-1 NMR, C-13 NMR, HR-ESI-MS and single-crystal X-ray diffraction The crystal of the title compound belongs to monoclinic, space group R3 with a = 34 255(5), b = 34 255(5), c = 6 8671(14) angstrom, beta = 90 degrees, Z = 9, V = 6978(2) angstrom(3), M-r = 490 70, D-c = 1 051 mg/m(3), mu = 0 069 mm (1), F(000) = 2430, R = 0 0375 and wR = 0 0808 The title compound is stacked into a three-dimensional network through hydrogen bonds

引用

页码：1798 / 1801

页数：4

共 50 条

[41] Crystal structure of the meta hydroxyl phenyl analog of alpha(+)-prodine
Cody, V
Li, NY
Khanolkar, AD
Makriyannis, A
Froimowitz, M
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1996, 26 (09) : 601 - 605
[42] Mapping nucleic acid structure by hydroxyl radical cleavage
Tullius, TD
Greenbaum, JA
CURRENT OPINION IN CHEMICAL BIOLOGY, 2005, 9 (02) : 127 - 134
[43] STRUCTURE OF GLYCOSIDES OF OLEANOLIC ACID ISOLATED FROM ROOTS OF CALENDULA-OFFICINALIS
WOJCIECHOWSKI, Z
JELONKIE.A
TOMASZEWSKI, M
JANKOWSKI, J
KASPRZYK, Z
PHYTOCHEMISTRY, 1971, 10 (05) : 1121 - +
[44] Influence of hydroxyl group in stabilizing the Schiff base crystal structure: Crystal structure, computational and molecular docking studies
Bhat, Dhruva
Spoorthy, L.
Sharanya, R.
Siddesh, M.
Mahesha
Kumar, A. H. Udaya
Lokanath, N. K.
JOURNAL OF MOLECULAR STRUCTURE, 2023, 1280
[45] Preparation, crystal structure and antibacterial activity of condensation products of usnic acid and acyl hydrazides
Sladic, D
Beljanski, V
Prelesnik, B
Bogdanovic, G
Ivanovic, I
Andjelkovic, K
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 1998, 63 (03) : 171 - 182
[46] A convenient preparation of aldonohydroxamic acids in water and crystal structure of L-erythronohydroxamic acid
Salmon, L
Prost, E
Merienne, C
Hardré, R
Morgant, G
CARBOHYDRATE RESEARCH, 2001, 335 (03) : 195 - 204
[47] PREPARATION, CRYSTAL-STRUCTURE AND PROPERTIES OF SPIROPHOSPHORANES DERIVED FROM HYDROXYCARBOXYLIC ACID AZIDES
POCHLAUER, P
HIMMER, C
PERINGER, P
MULLER, EP
JENNY, T
PETTER, W
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1987, 30 (1-2) : 455 - 458
[48] Preparation, crystal structure and antibacterial activity of condensation products of usnic acid and acyl hydrazides
Journal of the Serbian Chemical Society, 63 (03):
[49] Preparation and crystal structure of cobalt(II) complex with 3,5-pyridinedicarboxylic acid
Qu, XW
Liu, G
Zhang, LC
Li, L
Hu, HM
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2003, 24 (06): : 983 - 985
[50] Preparation and crystal structure of copper(I) carbonyl hydrogensulfate, obtained by carbonylation in sulphuric acid
Dell'Amico, DB
Calderazzo, F
Labella, L
Lorenzini, F
Marchetti, F
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (08): : 1868 - 1872

← 1 2 3 4 5 →