A green and highly efficient protocol for hydrolysis of substituted benzyl chloride using ionic liquid [bmim]BF4 as phase-transfer catalyst

被引：3
|
作者：
Zhang, Yong [1 ]
Zang, Hongjun [1 ]
Cheng, Bo-Wen [1 ]
机构：
[1] Tianjin Polytech Univ, Dept Enviroment & Chem Engn, Tianjin Municipal Key Lab Fiber Modificat & Funct, Tianjin 300160, Peoples R China
来源：
ENVIRONMENT MATERIALS AND ENVIRONMENT MANAGEMENT PTS 1-3 | 2010年 / 113-116卷
关键词：
benzyl chloride; alkaline hydrolysis; ionic liquid; ALKALINE-HYDROLYSIS;
D O I：
10.4028/www.scientific.net/AMR.113-116.1990
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Alkaline hydrolysis of substituted benzyl chloride (BzCl) in ionic liquid [bmini]BF(4) is investigated. The presence of the [bmim]BF4, increased the solubility of substituted BzCl in aqueous solutions and increased the selectivity toward the formation of benzyl alcohol. The main advantages of the present procedure are shorter time, higher yields, benignancy to environment and no by-products.
引用
收藏
页码：1990 / 1992
页数：3
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