Magnetic exchange interaction in triply bridged dinickel(II) complexes

被引：18

作者：

Loose, Claudia ^{[1
]}

Ruiz, Eliseo ^{[2
,3
]}

Kersting, Berthold ^{[4
]}

Kortus, Jens ^{[1
]}

机构：

[1] TU Bergakad Freiberg, Inst Theoret Phys, D-09599 Freiberg, Germany

[2] Univ Barcelona, Dept Quim Inorgan, Barcelona 08028, Spain

[3] Univ Barcelona, Inst Recerca Quim Teor & Computac, E-08028 Barcelona, Spain

[4] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany

来源：

CHEMICAL PHYSICS LETTERS | 2008年 / 452卷 / 1-3期

关键词：

D O I：

10.1016/j.cplett.2007.12.035

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We investigated the magnetic properties of a series of dinickel(II) complexes with hexaaza-dithiophenolate ligand [(L)Ni-2(mu-L')(n+) bridged by L' = N-3(-), BH4-, NO2-, acetato, benzoato and pyridazine using density functional theory calculations. We show that the experimental observed behavior can be understood with help of the Hay-Thibeault-Hoffmann model, where ferromagnetic coupling is related to the degeneracy of the magnetic orbitals. Further, we calculate the magnetic anisotropy parameters including spin-orbit coupling effects in a perturbative way. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：38 / 43

页数：6

共 50 条

[41] SYNTHESIS OF DOUBLY AND TRIPLY BRIDGED CHROMIUM ARENE PHOSPHITE COMPLEXES
KRIVYKH, VV
TOLSTAYA, MV
RYBINSKAYA, MI
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1986, 35 (10): : 2155 - 2157
[42] EXCHANGE OF CYCLOPALLADATED LIGANDS IN CHLORO-BRIDGED PALLADIUM(II) COMPLEXES
RYABOV, AD
YATSIMIRSKY, AK
INORGANIC CHEMISTRY, 1984, 23 (06) : 789 - 790
[43] Magnetic properties of pyrimidine-bridged copper(II) complexes
Ishida, Takayuki
Nakayama, Kensuke
Nakagawa, Mitsutoshi
Sato, Wataru
Ishikawa, Yoshimitsu
Yasui, Masanori
Iwasaki, Fujiko
Nogami, Takashi
Synthetic Metals, 85 (1-3): : 1655 - 1658
[44] Magnetic properties of pyrimidine-bridged copper(II) complexes
Ishida, T
Nakayama, K
Nakagawa, M
Sato, W
Ishikawa, Y
Yasui, M
Iwasaki, F
Nogami, T
SYNTHETIC METALS, 1997, 85 (1-3) : 1655 - 1658
[45] ESTIMATION OF MAGNETIC EXCHANGE COUPLING-CONSTANTS IN BRIDGED DIMER COMPLEXES
HART, JR
RAPPE, AK
GORUN, SM
UPTON, TH
JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (15): : 6264 - 6269
[46] Substituent effects on magnetic exchange in phenoxy-bridged dimanganese complexes
Kelley, Sarah E.
Fehir, Richard J., Jr.
McCusker, James K.
McCaffrey, Vanessa P.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
[47] Dinickel complexes bridged by unusual (N,O,O′)-coordinated α-amino acids:: syntheses, structural characterization and magnetic properties
Wang, L
Cai, JW
Mao, ZW
Feng, XL
Huang, JW
TRANSITION METAL CHEMISTRY, 2004, 29 (04) : 411 - 418
[48] Syntheses, molecular and supramolecular structures, electrochemistry and magnetic properties of two macrocyclic dinickel(II) complexes
Hazra, Susanta
Mondal, Suraj
Fleck, Michel
Sasmal, Sujit
Sanudo, E. Carolina
Mohanta, Sasankasekhar
POLYHEDRON, 2011, 30 (11) : 1906 - 1913
[49] Salicylaldimine Schiff bases - Generation of self-assembled and chiral complexes with Ni(II) and Zn(II) ions. An unusual antiferromagnetic interaction in a triply bridged Ni(II) dimer
Bhardwaj, Vimal K.
Hundal, Maninder Singh
Corbella, Montserrat
Gomez, Veronica
Hundal, Geeta
POLYHEDRON, 2012, 38 (01) : 224 - 234
[50] The importance of an additional water bridge in making the exchange coupling of bis(μ-phenoxo)dinickel(II) complexes ferromagnetic
Biswas, Rituparna
Kar, Paramita
Song, You
Ghosh, Ashutosh
DALTON TRANSACTIONS, 2011, 40 (19) : 5324 - 5331

← 1 2 3 4 5 →